Kornfield, Julia A. and Hule, Rohan and Kurji, Zuleikha and Pirogovsky, Paul (2013) Self-assembly of coil-liquid crystal (LC) diblocks in LC solvent: Hierarchies of anisotropies. In: 245th ACS National Meeting & Exposition, Abstracts of Papers, April 7-11, 2013, New Orleans, LA. https://resolver.caltech.edu/CaltechAUTHORS:20130408-154331705
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Abstract
Spontaneous anisotropy in the local chain conformation of Side-Group Liq. Cryst. Polymers (SGLCPs) drives the formation of anisotropic self-assembled microstructures of diblock copolymers consisting of an SGLCP block and a random coil block when dissolved in a small mol. LC, as obsd. by SANS and TEM. A phys.-inspired, segment-based model allows us to predict scattering profiles for different proposed arrangements of the block copolymers within the microstructure. Predicted scattering patterns, spanning the range from the overall assembly (>100nm) to the intrachain scale (5-100nm), are compared with the obsd. scattering profiles to discriminate between different possible self-assembled structures.
| Item Type: | Conference or Workshop Item (Paper) | ||||||
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| Additional Information: | © 2013 American Chemical Society. | ||||||
| Record Number: | CaltechAUTHORS:20130408-154331705 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20130408-154331705 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 37813 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Tony Diaz | ||||||
| Deposited On: | 12 Aug 2013 22:30 | ||||||
| Last Modified: | 03 Oct 2019 04:51 |
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