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Identification of a mid-infrared electronic absorption band of Fe^(2+) in the distorted M(2) site of Orthopyroxene, (Mg, Fe)SiO_3

Goldman, Don S. and Rossman, George R. (1976) Identification of a mid-infrared electronic absorption band of Fe^(2+) in the distorted M(2) site of Orthopyroxene, (Mg, Fe)SiO_3. Chemical Physics Letters, 41 (3). pp. 474-475. ISSN 0009-2614. https://resolver.caltech.edu/CaltechAUTHORS:20130416-101652804

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Abstract

An electronic absorption band of Fe^(2+) in the distorted, six-coordinate M(2) site of the common mineral orthopyroxene, (Mg, Fe)SiO_3, is identified at 2350 cm^(−1). This band is attributed to the A_1 → B_2 transition within the split ^5T_(2g) state of Fe^(2+) in C_(2V) symmetry.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1016/0009-2614(76)85396-1DOIUNSPECIFIED
http://www.sciencedirect.com/science/article/pii/0009261476853961PublisherUNSPECIFIED
ORCID:
AuthorORCID
Rossman, George R.0000-0002-4571-6884
Additional Information:© 1976 Elsevier. Received 5 February 1976. We thank J. Ito of the University of Chicago for supplying us with the synthetic magnesium, cobalt and manganese pyroxenes.
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Caltech Division of Geological and Planetary Sciences2699
Issue or Number:3
Record Number:CaltechAUTHORS:20130416-101652804
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20130416-101652804
Official Citation:Don S. Goldman, George R. Rossman, Identification of a mid-infrared electronic absorption band of Fe2+ in the distorted M(2) site of Orthopyroxene, (Mg, Fe)SiO3, Chemical Physics Letters, Volume 41, Issue 3, 1 August 1976, Pages 474-475, ISSN 0009-2614, 10.1016/0009-2614(76)85396-1. (http://www.sciencedirect.com/science/article/pii/0009261476853961)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:37962
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:16 Apr 2013 17:29
Last Modified:26 Nov 2019 11:15

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