CaltechAUTHORS
  A Caltech Library Service

A Dihydroxo-Bridged Ferric Dimer

Schugar, Harvey J. and Rossman, George R. and Gray, Harry B. (1969) A Dihydroxo-Bridged Ferric Dimer. Journal of the American Chemical Society, 91 (16). pp. 4564-4566. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20130430-092828269

[img]
Preview
PDF - Published Version
See Usage Policy.

369kB

Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20130430-092828269

Abstract

Recent investigations have produced a large number of dimeric complexes containing the oxo-bridged structural unit Fe_2O^(4+). Here we report the isolation and characterization of [Fe (pic)_2OH]_2 which apparently is the first example of a crystalline iron(III) dimer which utilizes dihydroxo bridging in its coordination structure.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja01044a052DOIUNSPECIFIED
http://pubs.acs.org/doi/abs/10.1021/ja01044a052PublisherUNSPECIFIED
ORCID:
AuthorORCID
Rossman, George R.0000-0002-4571-6884
Gray, Harry B.0000-0002-7937-7876
Additional Information:© 1969 American Chemical Society. Research at the California Institute of Technology was supported by the National Science Foundation; research at Rutgers University was supported by the Petroleum Research Fund and the Rutgers University Research Fund. We thank Professors R. Herber and J. Potenza for the Mössbauer and X-ray crystallographic measurements.
Funders:
Funding AgencyGrant Number
NSFUNSPECIFIED
Petroleum Research FundUNSPECIFIED
Rutgers University Research FundUNSPECIFIED
Issue or Number:16
Record Number:CaltechAUTHORS:20130430-092828269
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20130430-092828269
Official Citation:Dihydroxo-bridged ferric dimer Harvey Schugar J., George R. Rossman, and Harry B. Gray Journal of the American Chemical Society 1969 91 (16), 4564-4566
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:38175
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:30 Apr 2013 19:39
Last Modified:22 Nov 2019 09:58

Repository Staff Only: item control page