Schugar, Harvey J. and Rossman, George R. and Gray, Harry B. (1969) A Dihydroxo-Bridged Ferric Dimer. Journal of the American Chemical Society, 91 (16). pp. 4564-4566. ISSN 0002-7863. doi:10.1021/ja01044a052. https://resolver.caltech.edu/CaltechAUTHORS:20130430-092828269
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Abstract
Recent investigations have produced a large number of dimeric complexes containing the oxo-bridged structural unit Fe_2O^(4+). Here we report the isolation and characterization of [Fe (pic)_2OH]_2 which apparently is the first example of a crystalline iron(III) dimer which utilizes dihydroxo bridging in its coordination structure.
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| Additional Information: | © 1969 American Chemical Society. Research at the California Institute of Technology was supported by the National Science Foundation; research at Rutgers University was supported by the Petroleum Research Fund and the Rutgers University Research Fund. We thank Professors R. Herber and J. Potenza for the Mössbauer and X-ray crystallographic measurements. | |||||||||
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| Issue or Number: | 16 | |||||||||
| DOI: | 10.1021/ja01044a052 | |||||||||
| Record Number: | CaltechAUTHORS:20130430-092828269 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20130430-092828269 | |||||||||
| Official Citation: | Dihydroxo-bridged ferric dimer Harvey Schugar J., George R. Rossman, and Harry B. Gray Journal of the American Chemical Society 1969 91 (16), 4564-4566 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 38175 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Tony Diaz | |||||||||
| Deposited On: | 30 Apr 2013 19:39 | |||||||||
| Last Modified: | 09 Nov 2021 23:35 |
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