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A Dihydroxo-Bridged Ferric Dimer

Schugar, Harvey J. and Rossman, George R. and Gray, Harry B. (1969) A Dihydroxo-Bridged Ferric Dimer. Journal of the American Chemical Society, 91 (16). pp. 4564-4566. ISSN 0002-7863. doi:10.1021/ja01044a052.

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Recent investigations have produced a large number of dimeric complexes containing the oxo-bridged structural unit Fe_2O^(4+). Here we report the isolation and characterization of [Fe (pic)_2OH]_2 which apparently is the first example of a crystalline iron(III) dimer which utilizes dihydroxo bridging in its coordination structure.

Item Type:Article
Related URLs:
URLURL TypeDescription
Rossman, George R.0000-0002-4571-6884
Gray, Harry B.0000-0002-7937-7876
Additional Information:© 1969 American Chemical Society. Research at the California Institute of Technology was supported by the National Science Foundation; research at Rutgers University was supported by the Petroleum Research Fund and the Rutgers University Research Fund. We thank Professors R. Herber and J. Potenza for the Mössbauer and X-ray crystallographic measurements.
Funding AgencyGrant Number
Petroleum Research FundUNSPECIFIED
Rutgers University Research FundUNSPECIFIED
Issue or Number:16
Record Number:CaltechAUTHORS:20130430-092828269
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Official Citation:Dihydroxo-bridged ferric dimer Harvey Schugar J., George R. Rossman, and Harry B. Gray Journal of the American Chemical Society 1969 91 (16), 4564-4566
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:38175
Deposited By: Tony Diaz
Deposited On:30 Apr 2013 19:39
Last Modified:09 Nov 2021 23:35

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