Labotka, Theodore C. and Rossman, George R. (1974) The Infrared Pleochroism of Lawsonite: The Orientation of the Water and Hydroxide Groups. American Mineralogist, 59 (7-8). pp. 799-806. ISSN 0003-004X. https://resolver.caltech.edu/CaltechAUTHORS:20130513-100200531
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Abstract
Polarized infrared absorption spectra of thin single crystals of lawsonite, CaAI_2(OH)_2Si_2O_7H_2O_2, have been measured at room temperature and near 78 K. These data suggest a structural model in which the hydrogen atoms of both OH and H_2O lie in planes parallel to (001). The polanzat1on data demand that the order of the energies of the symmetric and antisymmetric stretch of the crystallographically ordered water in lawsonite be reversed from that of liquid water.
Item Type: | Article | ||||||
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Additional Information: | © 1974 Mineralogical Society of America. Manuscript received, December 26, 1973; accepted for publication, February 26, 1974. | ||||||
Group: | UNSPECIFIED, Division of Geological and Planetary Sciences | ||||||
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Issue or Number: | 7-8 | ||||||
Record Number: | CaltechAUTHORS:20130513-100200531 | ||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20130513-100200531 | ||||||
Official Citation: | The infrared pleochroism of lawsonite: The orientation of the water and hydroxide groups Theodore C. Labotka, and George R. Rossman 799-806 | ||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
ID Code: | 38443 | ||||||
Collection: | CaltechAUTHORS | ||||||
Deposited By: | Ruth Sustaita | ||||||
Deposited On: | 13 May 2013 17:17 | ||||||
Last Modified: | 03 Oct 2019 04:57 |
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