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H–H and Si–H Bond Addition to Fe≡NNR_2 Intermediates Derived from N_2

Suess, Daniel L. M. and Peters, Jonas C. (2013) H–H and Si–H Bond Addition to Fe≡NNR_2 Intermediates Derived from N_2. Journal of the American Chemical Society, 135 (13). pp. 4938-4941. ISSN 0002-7863. PMCID PMC3770781. doi:10.1021/ja400836u. https://resolver.caltech.edu/CaltechAUTHORS:20130523-114051847

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Abstract

The synthesis and characterization of Fe–diphosphineborane complexes are described in the context of N_2 functionalization chemistry. Iron aminoimides can be generated at room temperature under 1 atm N_2 and are shown to react with E–H bonds from PhSiH_3 and H_2. The resulting products derive from delivery of the E fragment to Nα and the H atom to B. The flexibility and lability of the Fe–BPh interactions in these complexes engender this reactivity.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja400836uDOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja400836uPublisherArticle
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770781PubMed CentralArticle
ORCID:
AuthorORCID
Peters, Jonas C.0000-0002-6610-4414
Additional Information:© 2013 American Chemical Society. Received: January 24, 2013; Published: March 11, 2013. Published In Issue April 03, 2013. We acknowledge the NIH (GM070757) and the Beckman Institute for funding and thank Lawrence Henling and Dr. Jens Kaiser for assistance with XRD studies. We also acknowledge the Gordon and Betty Moore Foundation, the Beckman Institute, and the Sanofi-Aventis BRP at Caltech for their support of the Molecular Observatory at Caltech. The SSRL is operated for the DOE and supported by its Office of Biological and Environmental Research, the NIH NIGMS (including P41GM103393), and the NCRR (P41RR001209).
Funders:
Funding AgencyGrant Number
NIHGM070757
Gordon and Betty Moore FoundationUNSPECIFIED
Caltech Sanofi-Aventis Bioengineering Research ProgramUNSPECIFIED
Department of Energy (DOE)UNSPECIFIED
NIHP41GM103393
NIHP41RR001209
Issue or Number:13
PubMed Central ID:PMC3770781
DOI:10.1021/ja400836u
Record Number:CaltechAUTHORS:20130523-114051847
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20130523-114051847
Official Citation:H–H and Si–H Bond Addition to Fe≡NNR2 Intermediates Derived from N2 Daniel L. M. Suess and Jonas C. Peters Journal of the American Chemical Society 2013 135 (13), 4938-4941
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:38659
Collection:CaltechAUTHORS
Deposited By: Jason Perez
Deposited On:24 May 2013 15:15
Last Modified:09 Nov 2021 23:39

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