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Hygroscopicity of secondary organic aerosols formed by oxidation of cycloalkenes, monoterpenes, sesquiterpenes, and related compounds

Varutbangkul, V. and Brechtel, F. J. and Bahreini, R. and Ng, N. L. and Keywood, M. D. and Kroll, J. H. and Flagan, R. C. and Seinfeld, J. H. and Lee, A. and Goldstein, A. H. (2006) Hygroscopicity of secondary organic aerosols formed by oxidation of cycloalkenes, monoterpenes, sesquiterpenes, and related compounds. Atmospheric Chemistry and Physics, 6 (9). pp. 2367-2388. ISSN 1680-7316. http://resolver.caltech.edu/CaltechAUTHORS:VARacp06

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Abstract

A series of experiments has been conducted in the Caltech indoor smog chamber facility to investigate the water uptake properties of aerosol formed by oxidation of various organic precursors. Secondary organic aerosol (SOA) from simple and substituted cycloalkenes (C5-C8) is produced in dark ozonolysis experiments in a dry chamber (RH~5%). Biogenic SOA from monoterpenes, sesquiterpenes, and oxygenated terpenes is formed by photooxidation in a humid chamber (~50% RH). Using the hygroscopicity tandem differential mobility analyzer (HTDMA), we measure the diameter-based hygroscopic growth factor (GF) of the SOA as a function of time and relative humidity. All SOA studied is found to be slightly hygroscopic, with smaller water uptake than that of typical inorganic aerosol substances. The aerosol water uptake increases with time early in the experiments for the cycloalkene SOA, but decreases with time for the sesquiterpene SOA. This behavior could indicate competing effects between the formation of more highly oxidized polar compounds (more hygroscopic), and formation of longer-chained oligomers (less hygroscopic). All SOA also exhibit a smooth water uptake with RH with no deliquescence or efflorescence. The water uptake curves are found to be fitted well with an empirical three-parameter functional form. The measured pure organic GF values at 85% RH are between 1.09–1.16 for SOA from ozonolysis of cycloalkenes, 1.01–1.04 for sesquiterpene photooxidation SOA, and 1.06–1.10 for the monoterpene and oxygenated terpene SOA. The GF of pure SOA (GForg) in experiments in which inorganic seed aerosol is used is determined by assuming volume-weighted water uptake (Zdanovskii-Stokes-Robinson or "ZSR" approach) and using the size-resolved organic mass fraction measured by the Aerodyne Aerosol Mass Spectrometer. Knowing the water content associated with the inorganic fraction yields GForg values. However, for each precursor, the GForg values computed from different HTDMA-classified diameters agree with each other to varying degrees. Comparing growth factors from different precursors, we find that GForg is inversely proportional to the precursor molecular weight and SOA yield, which is likely a result of the fact that higher-molecular weight precursors tend to produce larger and less hygroscopic oxidation products.


Item Type:Article
ORCID:
AuthorORCID
Ng, N. L.0000-0001-8460-4765
Flagan, R. C.0000-0001-5690-770X
Seinfeld, J. H.0000-0003-1344-4068
Additional Information:© 2006 Author(s). This work is licensed under a Creative Commons License. Published by Copernicus GmbH on behalf of the European Geosciences Union. Received: 14 December 2005 – Published in Atmos. Chem. Phys. Discuss.: 9 February 2006 Revised: 21 April 2006 – Accepted: 5 May 2006 – Published: 29 June 2006 This research was funded by the U.S. Environmental Protection Agency Science to Achieve Results (STAR) Program grant number RD-83107501-0, managed by EPA’s Office of Research and Development (ORD), National Center for Environmental Research (NCER), and by U.S. Department of Energy Biological and Environmental Research Program DE-FG02-05ER63983. The University of California contributions to this work were supported by the National Science Foundation Atmospheric Chemistry Program (Awards ATM-0119510 and ATM-0443448) and the California Air Resources Board (Contract 00-732). F. J. Brechtel was supported by the National Science Foundation Atmospheric Chemistry Program under Award ATM-0333817. The authors thank D. Collins of Texas A&M University and C. Stanier of University of Iowa for helpful discussions.
Funders:
Funding AgencyGrant Number
Environmental Protection Agency (EPA)RD-83107501-0
Department of Energy (DOE)DE-FG02-05ER63983
NSFATM-0119510
NSFATM-0443448
California Air Resources Board00-732
NSFATM-0333817
Record Number:CaltechAUTHORS:VARacp06
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:VARacp06
Alternative URL:http://www.atmos-chem-phys.net/6/2367/2006/acp-6-2367-2006.html
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ID Code:3950
Collection:CaltechAUTHORS
Deposited By: Archive Administrator
Deposited On:20 Jul 2006
Last Modified:04 Apr 2017 20:46

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