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New precatalysts for olefin polymerization having LX2 pincer ligands

Bercaw, John E. and Labinger, Jay A. and Tonks, Ian and Winston, Matthew S. and Klet, Rachel C. and Lenton, Taylor N. and Despagnet-Ayoub, Emmanuelle (2013) New precatalysts for olefin polymerization having LX2 pincer ligands. In: 245th ACS National Meeting & Exposition, Abstracts of Papers, April 7-11, 2013, New Orleans, LA.

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Post metallocene zirconium and titanium catalysts with tridentate bis(phenolate)-donor (donor = pyridine, furan, and thiophene) "LX2" pincer ligands have been investigated as propylene and ethylene polymn. catalysts. Analogous Ti, Zr, Ta, and lanthanide complexes with pincer ligands having thiophenolate, anilide, and phospha-anilide X type ligands, as well as those having Nheterocyclic carbene L type donors have been prepd., and their performance as catalysts for olefin polymns. has been explored.

Item Type:Conference or Workshop Item (Paper)
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URLURL TypeDescription
Labinger, Jay A.0000-0002-1942-9232
Despagnet-Ayoub, Emmanuelle0000-0002-9013-7574
Additional Information:© 2013 American Chemical Society.
Record Number:CaltechAUTHORS:20130723-083102363
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:39511
Deposited By: Tony Diaz
Deposited On:19 Aug 2013 21:45
Last Modified:03 Oct 2019 05:07

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