Radlauer, Madalyn R. and Buckley, Aya K. and Agapie, Theodor (2013) Copolymerization of amino olefins with ethylene by dinickel bisphenoxyiminato complexes. In: 245th ACS National Meeting & Exposition, Abstracts of Papers, April 7-11, 2013, New Orleans, LA. https://resolver.caltech.edu/CaltechAUTHORS:20130724-153502539
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Abstract
Dinickel bisphenoxyiminato complexes based on 1,4 and 1,3 terphenyl backbones were synthesized. Substitution of the central arene ortho to the side aryl moieties allowed isolation of syn and anti atropisomers. The syn atropisomers of the reported complexes afforded copolymn. of amino olefins with ethylene in the presence of a phosphine scavenger (Ni(COD)_2). The ability of the syn atropisomers of these complexes to incorporate unprotected amino olefins by insertion polymn. was investigated by comparisons of the syn and anti atropisomers, and the 1,3 and 1,4 terphenyl systems. Further insight regarding the mechanism of polymn. with the reported complexes was obtained by copolymns. of ethylene and 1-hexene in the presence of a variety of non-olefinic amines.
| Item Type: | Conference or Workshop Item (Paper) | ||||||
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| Additional Information: | © 2013 American Chemical Society. | ||||||
| Record Number: | CaltechAUTHORS:20130724-153502539 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20130724-153502539 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 39567 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Tony Diaz | ||||||
| Deposited On: | 19 Aug 2013 21:51 | ||||||
| Last Modified: | 09 Mar 2020 13:19 |
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