Labinger, Jay A. (2013) Two approaches to selective oligomerization of light alkenes. In: 245th ACS National Meeting & Exposition, Abstracts of Papers, April 7-11, 2013, New Orleans, LA. https://resolver.caltech.edu/CaltechAUTHORS:20130725-100027462
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Abstract
There is currently much interest in developing methodol. for upgrading light (C_(2-5)) hydrocarbons to more valuable fuels. Schemes based on alkene oligomerization are attractive, but accomplishing that selectively is a challenging requirement. We have been studying two very different systems: an air- and water-stable hydroxy-bridged dimeric Pd(II) complex that selfactivates to generate an oligomerization catalyst; and bis(phosphine)Cr(III) complexes that catalyze selective ethylene trimerization upon activation with MAO. I will discuss recent mechanistic findings and their implications for potential applicability to desirable conversion processes.
| Item Type: | Conference or Workshop Item (Paper) | ||||||
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| Additional Information: | © 2013 American Chemical Society. | ||||||
| Record Number: | CaltechAUTHORS:20130725-100027462 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20130725-100027462 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 39582 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Tony Diaz | ||||||
| Deposited On: | 19 Aug 2013 21:53 | ||||||
| Last Modified: | 03 Oct 2019 05:08 |
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