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Compositions of large metal nodules in mesosiderites: Links to iron meteorite group IIIAB and the origin of mesosiderite subgroups

Hassanzadeh, Jamshid and Rubin, Alan E. and Wasson, John T. (1990) Compositions of large metal nodules in mesosiderites: Links to iron meteorite group IIIAB and the origin of mesosiderite subgroups. Geochimica et Cosmochimica Acta, 54 (11). pp. 3197-3208. ISSN 0016-7037. https://resolver.caltech.edu/CaltechAUTHORS:20130821-103617723

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Abstract

Large mesosiderite metal nodules were studied petrographically and by neutron activation; their large sizes minimized the effects of silicate contamination and dilution by Fe reduced from FeO. The remarkable mixture of subequal amounts of metal and basaltic and pyroxenitic silicates in mesosiderites can be explained by the accretion of a core-like metal mass from one asteroid onto the surface of another asteroid; our data show that the accreted mass had a composition roughly similar to that of the IIIAB iron-meteorite core, consistent with other evidence of close genetic links between these and other related groups. The siderophile compositional pattern, the very limited compositional range, the (inferred) large projectile/target ratio, and the electrical interconnectedness of mesosiderite metal indicate that the bulk of the metal was molten when accreted. Mesosiderites have been divided into plagioclase- and tridymiterich subgroup A and orthopyroxene-rich subgroup B on the basis of modal silicate mineralogy. Roughly the same subgroups are defined by metal compositions; Au, As, Ni, and Cu are generally higher, and W lower in subgroup A than in subgroup B. In our sample set, a Widmanstätten pattern is only observed in nodules from subgroup A. A plausible model is that subgroup A best preserves the compositions of the target regolithic silicates and accreted core; subgroup B is comprised of these materials together with a minor amount of coremantle materials consisting of olivine and refractory, Ni-poor metal. The independent covariation of Ga, Re, and Ir may in part reflect fractionations during impact heating events. The anomalous mesosiderite Reckling Peak A79015 is strongly depleted in refractory siderophiles and slightly enriched in volatile siderophiles; such evolved metal requires a formation distinct from common mesosiderite metal.


Item Type:Article
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http://dx.doi.org/10.1016/0016-7037(90)90134-7DOIArticle
http://www.sciencedirect.com/science/article/pii/0016703790901347PublisherArticle
Additional Information:© 1990 Pergamon Press. Received April 10, 1989; accepted in revised form August 29, 1990. We thank R. E. Jones, J. Ma, X. Ouyang, and T. Jen for technical assistance; R. N. Clayton for his unpublished O-isotope analysis of RKPA790 15; and R. S. Clarke, C. B. Moore, H. Pedersen, P. Pellas, A. W. R. Bevan, and T. B. Thomas for provision of the samples. R. W. Bild. D. W. Mittlefehldt. R. S. Clarke, R. H. Hewins, and E. R. D. Scott generously shared ideas and observations with us. We thank C. R. Chapman and M. Prim for useful and spirited reviews. This work was supported in part by NASA grant NAG 9-40.
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Funding AgencyGrant Number
NASANAG 9-40
Issue or Number:11
Record Number:CaltechAUTHORS:20130821-103617723
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20130821-103617723
Official Citation:Jamshid Hassanzadeh, Alan E. Rubin, John T. Wasson, Compositions of large metal nodules in mesosiderites: Links to iron meteorite group IIIAB and the origin of mesosiderite subgroups, Geochimica et Cosmochimica Acta, Volume 54, Issue 11, November 1990, Pages 3197-3208, ISSN 0016-7037, http://dx.doi.org/10.1016/0016-7037(90)90134-7.
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:40754
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:20 Sep 2013 20:11
Last Modified:03 Oct 2019 05:42

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