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An Approach to 8-Membered, 16-Membered and 24-Membered Sulfur- Containing Heterocycles Via Homolytic Cycloaddition of Alkynes with Butane-1,4-Dithiol

Troyansky, Emmanuil I. and Ismagilov, Rustem F. and Korneeva, Ekaterina N. and Pogosyan, Mariam S. and Nikishin, Gennady I. (1995) An Approach to 8-Membered, 16-Membered and 24-Membered Sulfur- Containing Heterocycles Via Homolytic Cycloaddition of Alkynes with Butane-1,4-Dithiol. Mendeleev Communications, 5 (1). pp. 18-20. ISSN 0959-9436. doi:10.1070/MC1995v005n01ABEH000441. https://resolver.caltech.edu/CaltechAUTHORS:20130821-160734243

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Abstract

Homolytic cycloaddition of butane-1,4-dithiol with alkynes offers a facile one-pot route to 8-membered 1,4-dithiocanes and 16-and 24-membered crown thioethers, 1,4,9,12-tetrathiacyclohexadecanes and 1,4,9,12,17,20-hexathiacyclotetracosanes.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1070/MC1995v005n01ABEH000441DOIArticle
http://www.sciencedirect.com/science/article/pii/S0959943695714596PublisherArticle
ORCID:
AuthorORCID
Ismagilov, Rustem F.0000-0002-3680-4399
Additional Information:Copyright © 1995 jointly by The Russian Academy of Sciences and The Royal Society of Chemistry (Turpion Ltd). Received 15 November 1994. Available online 11 March 2008. The authors are indebted for financial support to the Russian Foundation for Fundamental Research (project no. 93-03-18110) and the International Science Foundation (grant no. MPL000).
Funders:
Funding AgencyGrant Number
Russian Foundation for Fundamental Studies93-03-18110
International Science FoundationMPL000
Subject Keywords:crown thioethers; macrocyclization; construction; route
Issue or Number:1
DOI:10.1070/MC1995v005n01ABEH000441
Record Number:CaltechAUTHORS:20130821-160734243
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20130821-160734243
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:40883
Collection:CaltechAUTHORS
Deposited By: Whitney Barlow
Deposited On:29 Aug 2013 20:40
Last Modified:10 Nov 2021 04:23

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