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Homolytic cycloaddition of dithiols to alkynes leading to sulfur-containing heterocycles and crown thioethers: new comments to the mechanism

Troyansky, Emmanuil I. and Ismagilov, Rustem F. and Samoshin, Vyacheslav V. (1997) Homolytic cycloaddition of dithiols to alkynes leading to sulfur-containing heterocycles and crown thioethers: new comments to the mechanism. Sulfur Letters, 20 (5). pp. 219-224. ISSN 0278-6117. https://resolver.caltech.edu/CaltechAUTHORS:20130821-160734554

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Abstract

Multicenter three-electron (3e-2c) S-S bond formation can be employed to explain the cyclization in the homolytic addn. of α,ω-thiols to alkynes.


Item Type:Article
ORCID:
AuthorORCID
Ismagilov, Rustem F.0000-0002-3680-4399
Issue or Number:5
Record Number:CaltechAUTHORS:20130821-160734554
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20130821-160734554
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:40885
Collection:CaltechAUTHORS
Deposited By: Whitney Barlow
Deposited On:29 Aug 2013 21:30
Last Modified:03 Oct 2019 05:44

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