Cannon, Jeffrey S. and Grubbs, Robert H. (2013) Alkene Chemoselectivity in Ruthenium-Catalyzed Z-Selective Olefin Metathesis. Angewandte Chemie International Edition, 52 (34). pp. 9001-9004. ISSN 1433-7851. PMCID PMC3826562. doi:10.1002/anie.201302724. https://resolver.caltech.edu/CaltechAUTHORS:20130913-135632034
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Abstract
Chelated ruthenium catalysts can facilitate highly chemoselective olefin metathesis. Terminal and internal Z olefins reacted selectively to form new Z olefins in the presence of internal E olefins. Chemoselectivity for terminal olefins was also observed over both sterically hindered and electronically deactivated alkenes.
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| Additional Information: | © 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Received: April 2, 2013; Revised: May 10, 2013; Published online: July 5, 2013. This work was financially supported by the NIH (R01GM031332 and N.R.S.A. to J.S.C.: F32GM103002), and the NSF (CHE-1212767). NMR spectra were obtained by instruments supported by the NIH (RR027690). Materia Inc. is acknowledged for the generous donation of metathesis catalysts 1, 2, 5, and 6. | ||||||||||||
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| Subject Keywords: | chemoselectivity; macrocycles; metathesis; ruthenium; unconjugated dienes | ||||||||||||
| Issue or Number: | 34 | ||||||||||||
| PubMed Central ID: | PMC3826562 | ||||||||||||
| DOI: | 10.1002/anie.201302724 | ||||||||||||
| Record Number: | CaltechAUTHORS:20130913-135632034 | ||||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20130913-135632034 | ||||||||||||
| Official Citation: | Cannon, J. S. and Grubbs, R. H. (2013), Alkene Chemoselectivity in Ruthenium-Catalyzed Z-Selective Olefin Metathesis . Angew. Chem. Int. Ed., 52: 9001–9004. doi: 10.1002/anie.201302724 | ||||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
| ID Code: | 41327 | ||||||||||||
| Collection: | CaltechAUTHORS | ||||||||||||
| Deposited By: | Tony Diaz | ||||||||||||
| Deposited On: | 16 Sep 2013 21:05 | ||||||||||||
| Last Modified: | 10 Nov 2021 04:28 |
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