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Carbon nanotubes as electronic interconnects in solid acid fuel cell electrodes

Varga, Áron and Pfohl, Moritz and Brunelli, Nicholas A. and Schreier, Marcel and Giapis, Konstantinos P. and Haile, Sossina M. (2013) Carbon nanotubes as electronic interconnects in solid acid fuel cell electrodes. Physical Chemistry Chemical Physics, 15 (37). pp. 15470-15476. ISSN 1463-9076. https://resolver.caltech.edu/CaltechAUTHORS:20130924-085817202

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Abstract

Carbon nanotubes have been explored as interconnects in solid acid fuel cells to improve the link between nanoscale Pt catalyst particles and macroscale current collectors. The nanotubes were grown by chemical vapor deposition on carbon paper substrates, using nickel nanoparticles as the catalyst, and were characterized using scanning electron microscopy and Raman spectroscopy. The composite electrode material, consisting of CsH_2PO_4, platinum nanoparticles, and platinum on carbon-black nanoparticles, was deposited onto the nanotube-overgrown carbon paper by electrospraying, forming a highly porous, fractal structure. AC impedance spectroscopy in a symmetric cell configuration revealed a significant reduction of the electrode impedance as compared to similarly prepared electrodes without carbon nanotubes.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1039/C3CP52586DDOIArticle
http://pubs.rsc.org/en/Content/ArticleLanding/2013/CP/c3cp52586dPublisherArticle
ORCID:
AuthorORCID
Giapis, Konstantinos P.0000-0002-7393-298X
Haile, Sossina M.0000-0002-5293-6252
Additional Information:© 2013 Royal Society of Chemistry. Received 27th March 2013; Accepted 12th July 2013. This material is based upon work supported by the National Science Foundation under Grant No. DMR-0520565. Funding was also provided by the Gordon and Betty Moore Foundation through the Caltech Center for Sustainable Energy Research and by LiOx corporation. M.P. and M.S. were partially supported by ETH Zurich fellowships. The authors thank Prof. George Rossman for invaluable assistance with Raman spectroscopy measurements. We are also indebted to Prof. Harry Gray, without whose generosity this work would not have been possible.
Funders:
Funding AgencyGrant Number
NSFDMR-0520565
Gordon and Betty Moore FoundationUNSPECIFIED
Caltech Center for Sustainable Energy ResearchUNSPECIFIED
LiOx corporationUNSPECIFIED
ETH ZurichUNSPECIFIED
Issue or Number:37
Record Number:CaltechAUTHORS:20130924-085817202
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20130924-085817202
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:41490
Collection:CaltechAUTHORS
Deposited By: Jason Perez
Deposited On:24 Sep 2013 19:53
Last Modified:03 Oct 2019 05:49

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