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A CO-Derived Iron Dicarbyne That Releases Olefin upon Hydrogenation

Suess, Daniel L. M. and Peters, Jonas C. (2013) A CO-Derived Iron Dicarbyne That Releases Olefin upon Hydrogenation. Journal of the American Chemical Society, 135 (34). pp. 12580-12583. ISSN 0002-7863. PMCID PMC3794666. doi:10.1021/ja406874k. https://resolver.caltech.edu/CaltechAUTHORS:20131002-111755379

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Abstract

An iron diphosphineborane platform that was previously reported to facilitate a high degree of N_2 functionalization is herein shown to effect reductive CO coupling. Disilylation of an iron dicarbonyl precursor furnishes a structurally unprecedented iron dicarbyne complex. Several complexes related to this process are also characterized which allows for a comparative analysis of their respective Fe–B and Fe–C bonding. Facile hydrogenation of the iron dicarbyne at ambient temperature and 1 atm H_2 results in release of a CO-derived olefin.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja406874k DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja406874kPublisherArticle
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3794666PubMed CentralArticle
ORCID:
AuthorORCID
Peters, Jonas C.0000-0002-6610-4414
Additional Information:© 2013 American Chemical Society. Received: July 5, 2013; Published: August 9, 2013. We acknowledge the NIH (GM070757) and the Beckman Institute for funding and thank Lawrence Henling for assistance with XRD studies.
Funders:
Funding AgencyGrant Number
NIHGM070757
Beckman InstituteUNSPECIFIED
Issue or Number:34
PubMed Central ID:PMC3794666
DOI:10.1021/ja406874k
Record Number:CaltechAUTHORS:20131002-111755379
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20131002-111755379
Official Citation:A CO-Derived Iron Dicarbyne That Releases Olefin upon Hydrogenation Daniel L. M. Suess and Jonas C. Peters Journal of the American Chemical Society 2013 135 (34), 12580-12583
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:41610
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:02 Oct 2013 21:10
Last Modified:10 Nov 2021 04:32

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