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Chelates of β-diketones. VI. Synthesis and characterization of dimeric dialkoxo-bridged iron(III) complexes with acetylacetone and 2,2,6,6-tetramethylheptane-3,5-dione (HDPM)

Wu, Chin-Hua S. and Rossman, George R. and Gray, Harry B. and Hammond, George S. and Schugar, Harvey J. (1972) Chelates of β-diketones. VI. Synthesis and characterization of dimeric dialkoxo-bridged iron(III) complexes with acetylacetone and 2,2,6,6-tetramethylheptane-3,5-dione (HDPM). Inorganic Chemistry, 11 (5). pp. 990-994. ISSN 0020-1669. http://resolver.caltech.edu/CaltechAUTHORS:20131016-112104329

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Abstract

A series of compounds assigned the structure [L_2FeOR]_2 where L is the enolate of acetylacetone or dipivaloylmethane (HDPM) and R is CH_3, C_2H_5, and i-C_8H_7 has been prepared and characterized. They are obtained by the oxidation of ferrous compounds in alcoholic solutions containing free ligand and bases or directly from ferric compounds. These dimers are weakly antiferromagnetic (- J ≅ 10 cm^(-1)). Their infrared and optical spectroscopic properties are reported.


Item Type:Article
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http://dx.doi.org/10.1021/ic50111a015 DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ic50111a015PublisherArticle
ORCID:
AuthorORCID
Rossman, George R.0000-0002-4571-6884
Additional Information:© 1972 American Chemical Society. Received October 18, 1971. Research at the California Institute of Technology was supported by grants from the National Institutes of Health and the National Science Foundation. Research at Rutgers University was supported by the Rutgers Research Council and a Petroleum Research Fund starter grant.
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Rutgers Research Council UNSPECIFIED
American Chemical Society Petroleum Research FundUNSPECIFIED
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Caltech Arthur Amos Noyes Laboratory of Chemical Physics4245
Record Number:CaltechAUTHORS:20131016-112104329
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20131016-112104329
Official Citation:Chelates of .beta.-diketones. VI. Synthesis and characterization of dimeric dialkoxo-bridged iron(III) complexes with acetylacetone and 2,2,6,6-tetramethylheptane-3,5-dione (HDPM) Chin-Hua S. Wu, George R. Rossman, Harry B. Gray, George S. Hammond, and Harvey J. Schugar Inorganic Chemistry 1972 11 (5), 990-994
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:41946
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:16 Oct 2013 19:31
Last Modified:11 Mar 2017 03:28

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