Sullivan, Alexandra H. and Keitz, Benjamin K. and Grubbs, Robert H. (2013) Preparation of rapidly initiating ruthenium based olefin metathesis catalysts. In: 245th ACS National Meeting & Exposition, Abstracts of Papers, April 7-11, 2013, New Orleans, LA. https://resolver.caltech.edu/CaltechAUTHORS:20131101-090843903
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Abstract
Z-selective olefin metathesis ruthenium catalysts are highly sought after, due to their wide applications in both pharmaceuticals and materials science. A crucial step towards the prepn. of rapidly initiating, Z-selective, olefin metathesis catalysts was found to be the addn. of sodium pivalate to phosphonium alkyidene catalyst 1, resulting in the formation of the C-H activated complex 2 after two days of heating. Prepn. of 2, a close analog to the target catalyst 4, promises that future synthesis of 4 should be facile.
| Item Type: | Conference or Workshop Item (Paper) | ||||||
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| Additional Information: | © 2013 American Chemical Society. | ||||||
| Record Number: | CaltechAUTHORS:20131101-090843903 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20131101-090843903 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 42177 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Tony Diaz | ||||||
| Deposited On: | 01 Nov 2013 17:46 | ||||||
| Last Modified: | 03 Oct 2019 05:56 |
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