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Isotopic analyses of nitrogenous compounds from the Murchison meteorite: Ammonia, amines, amino acids, and polar hydrocarbons

Pizzarello, S. and Feng, X. and Epstein, S. and Cronin, J. R. (1994) Isotopic analyses of nitrogenous compounds from the Murchison meteorite: Ammonia, amines, amino acids, and polar hydrocarbons. Geochimica et Cosmochimica Acta, 58 (24). pp. 5579-5587. ISSN 0016-7037. https://resolver.caltech.edu/CaltechAUTHORS:20131113-125643116

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Abstract

The combined volatile bases (ammonia, aliphatic amines, and possibly other bases), ammonia, amino acids, and polar hydrocarbons were prepared from the Murchison meteorite for isotopic analyses. The volatile bases were obtained by cryogenic transfer after acid-hydrolysis of a hot-water extract and analyzed by combined gas chromatography-mass spectrometry of pentafluoropropionyl derivatives. The aliphatic amines present in this preparation comprise a mixture that includes both primary and secondary isomers through C_5 at a total concentration of ≥ 100 nmoles g^(−1). As commonly observed for meteoritic organic compounds, almost all isomers through C_5 are present, and the concentrations within homologous series decrease with increasing chain length. Ammonia was chromatographically separated from the other volatile bases and found at a concentration of 1.1–1.3 μmol g^(−1) meteorite. The ammonia analyzed includes contributions from ammonium salts and the hydrolysis of extractable organic compounds, e.g., carboxamides. Stable isotope analyses showed the volatile bases to be substantially enriched in the heavier isotopes, relative to comparable terrestrial compounds (δD ≤ + 1221%.; δ^(13)C = + 22%.; δ(15)N = + 93%.). Ammonia, per se, was found to have a somewhat lower δ^(15)N value (+69%.) than the total volatile bases; consequently, a higher δ^(15)N (>93%.) can be inferred for the other bases, which include the amines. Solvent-extractable polar hydrocarbons obtained separately were found to be enriched in ^(15)N (δ^(15)N = + 104%.). Total amino acids, prepared from a hydrolyzed hot-water extract by cation exchange chromatography, gave a δ^(15)N of + 94%., a value in good agreement with that obtained previously. Nitrogen isotopic data are also given for amino acid fractions separated chromatographically. The δ^(15)N values of the Murchison soluble organic compounds analyzed to date fall within a rather narrow range (δ^(15)N = + 94 ± 8%.), an observation consistent with their formation, or formation of their precursors, by interstellar chemistry.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1016/0016-7037(94)90251-8DOIArticle
http://www.sciencedirect.com/science/article/pii/0016703794902518PublisherArticle
Additional Information:© 1994 Elsevier Science Ltd. Received October 27, 1993: accepted in revised form August 25, 1994. 0ur thanks go to the National Aeronautics and Space Administration for financial support provided through grants NAG 9-46 (S.E.). NAGW-3329 (S.E.). and NAGW-1899 (J.R.C.), to the Center for Meteorite Studies of Arizona State University for providing samples of the Murchison meteorite from its collections, and to Mike Engel and John Kerridge for thorough reviews that led to a significantly improved manuscript. This is contribution number 127 from the Arizona State University Center for Meteorite Studies.
Funders:
Funding AgencyGrant Number
NASANAG 9-46
NASANAGW-3329
NASANAGW-1899
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Center for Meteorite Studies127
Issue or Number:24
Record Number:CaltechAUTHORS:20131113-125643116
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20131113-125643116
Official Citation:S. Pizzarello, X. Feng, S. Epstein, J.R. Cronin, Isotopic analyses of nitrogenous compounds from the Murchison meteorite: ammonia, amines, amino acids, and polar hydrocarbons, Geochimica et Cosmochimica Acta, Volume 58, Issue 24, December 1994, Pages 5579-5587, ISSN 0016-7037, http://dx.doi.org/10.1016/0016-7037(94)90251-8. (http://www.sciencedirect.com/science/article/pii/0016703794902518)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:42428
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:13 Nov 2013 21:30
Last Modified:03 Oct 2019 05:58

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