Whitesides, George M. and Nordlander, J. Eric and Roberts, John D.
(1962)
Nuclear Magnetic Resonance Spectroscopy. Structure and Dynamic Character of Allylic Grignard Reagents.
Discussions of the Faraday Society, 34
.
pp. 185-190.
ISSN 0366-9033.
doi:10.1039/DF9623400185.
https://resolver.caltech.edu/CaltechAUTHORS:20131211-095900745
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Abstract
Studies have been made of the nuclear magnetic resonance spectra of several allylic Grignard
reagents. The Grignard reagent prepared from γ,γ-dimethylallyl bromide appears best formulated
as an equilibrium mixture of γ,γ-dimethylallylmagnesium bromide and α,α-dimethylallylmagnesium
bromide, in which the former is the major component. The rate of interconversion of the allylic
isomers is rapid on the n.m.r. time scale at room temperature, but slow at -40°.
| Item Type: | Article |
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| Additional Information: | © 1962 Royal Society of Chemistry.
Received 1st June, 1962.
Supported in part by the Office of Naval Research. |
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| Funders: | | Funding Agency | Grant Number |
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| Office of Naval Research (ONR) | UNSPECIFIED |
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| Other Numbering System: | | Other Numbering System Name | Other Numbering System ID |
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| Caltech Gates and Crellin Laboratories of Chemistry | 2847 |
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| DOI: | 10.1039/DF9623400185 |
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| Record Number: | CaltechAUTHORS:20131211-095900745 |
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| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20131211-095900745 |
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| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. |
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| ID Code: | 42948 |
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| Collection: | CaltechAUTHORS |
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| Deposited By: |
Tony Diaz
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| Deposited On: | 11 Dec 2013 20:05 |
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| Last Modified: | 10 Nov 2021 16:30 |
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