Cheng, Mu-Jeng and Fu, Ross and Goddard, William A., III (2013) Design and validation of non-metal oxo complexes for C–H activation. Chemical Communications, 50 (14). pp. 1748-1750. ISSN 1359-7345. doi:10.1039/c3cc47502f. https://resolver.caltech.edu/CaltechAUTHORS:20140109-120001059
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Abstract
We use our recent discovery of the reduction-coupled oxo activation (ROA) principle to design a series of organometallic molecules that activate C–H bonds through this unique proton/electron-decoupled hydrogen abstraction mechanism, in which the main group oxo moiety binds to the proton while the electron is transferred to the transition metal. Here we illustrate this general class of catalyst clusters with several examples that are validated through quantum mechanics calculations.
| Item Type: | Article | |||||||||
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| Additional Information: | © 2014 The Royal Society of Chemistry. Received 30th September 2013; Accepted 17th December 2013; First published online 18 Dec 2013. Financial support from the Center for Catalytic Hydrocarbon Functionalization, an Energy Frontier Research Center, DOE DE-SC0001298, is gratefully acknowledged. | |||||||||
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| Issue or Number: | 14 | |||||||||
| DOI: | 10.1039/c3cc47502f | |||||||||
| Record Number: | CaltechAUTHORS:20140109-120001059 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20140109-120001059 | |||||||||
| Official Citation: | Cheng, M.-J., Fu, R., & Goddard, I. I. I. W. A. (2014). Design and validation of non-metal oxo complexes for C-H activation. Chemical Communications, 50(14), 1748-1750. doi: 10.1039/c3cc47502f | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 43296 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Tony Diaz | |||||||||
| Deposited On: | 10 Jan 2014 17:30 | |||||||||
| Last Modified: | 10 Nov 2021 16:35 |
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