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Gas Phase Production and Loss of Isoprene Epoxydiols

Bates, Kelvin H. and Crounse, John D. and St. Clair, Jason M. and Bennett, Nathan B. and Nguyen, Tran B. and Seinfeld, John H. and Stoltz, Brian M. and Wennberg, Paul O. (2014) Gas Phase Production and Loss of Isoprene Epoxydiols. Journal of Physical Chemistry A, 118 (7). pp. 1237-1246. ISSN 1089-5639. https://resolver.caltech.edu/CaltechAUTHORS:20140210-145231305

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Abstract

Isoprene epoxydiols (IEPOX) form in high yields from the OH-initiated oxidation of isoprene under low-NO conditions. These compounds contribute significantly to secondary organic aerosol formation. Their gas-phase chemistry has, however, remained largely unexplored. In this study, we characterize the formation of IEPOX isomers from the oxidation of isoprene by OH. We find that cis-β- and trans-β-IEPOX are the dominant isomers produced, and that they are created in an approximate ratio of 1:2 from the low-NO oxidation of isoprene. Three isomers of IEPOX, including cis-β- and trans-β, were synthesized and oxidized by OH in environmental chambers under high- and low-NO conditions. We find that IEPOX reacts with OH at 299 K with rate coefficients of (0.84 ± 0.07) × 10^(–11), (1.52 ± 0.07) × 10^(–11), and (0.98 ± 0.05) × 10^(–11) cm^3 molecule^(–1) s^(–1) for the δ1, cis-β, and trans-β isomers. Finally, yields of the first-generation products of IEPOX + OH oxidation were measured, and a new mechanism of IEPOX oxidation is proposed here to account for the observed products. The substantial yield of glyoxal and methylglyoxal from IEPOX oxidation may help explain elevated levels of those compounds observed in low-NO environments with high isoprene emissions.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://pubs.acs.org/doi/abs/10.1021/jp4107958PublisherArticle
http://dx.doi.org/10.1021/jp4107958DOIArticle
ORCID:
AuthorORCID
Bates, Kelvin H.0000-0001-7544-9580
Crounse, John D.0000-0001-5443-729X
St. Clair, Jason M.0000-0002-9367-5749
Seinfeld, John H.0000-0003-1344-4068
Stoltz, Brian M.0000-0001-9837-1528
Wennberg, Paul O.0000-0002-6126-3854
Additional Information:© 2014 American Chemical Society. Received: November 1, 2013; Revised: January 28, 2014; Published: January 29, 2014. The authors would like to thank Prof. Jason D. Surratt for correspondence regarding the synthesis of IEPOX and the National Science Foundation (AGS 1240604) for their support of this research.
Funders:
Funding AgencyGrant Number
NSFAGS-1240604
Issue or Number:7
Record Number:CaltechAUTHORS:20140210-145231305
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140210-145231305
Official Citation:Gas Phase Production and Loss of Isoprene Epoxydiols Kelvin H. Bates, John D. Crounse, Jason M. St. Clair, Nathan B. Bennett, Tran B. Nguyen, John H. Seinfeld, Brian M. Stoltz, and Paul O. Wennberg The Journal of Physical Chemistry A 2014 118 (7), 1237-1246
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:43756
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:10 Feb 2014 23:22
Last Modified:09 Mar 2020 13:19

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