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Biogenic and biomass burning organic aerosol in a boreal forest at Hyytiälä, Finland, during HUMPPA-COPEC 2010

Corrigan, A. L. and Russell, L. M. and Takahama, S. and Äijälä, M. and Ehn, M. and Junninen, H. and Rinne, J. and Petäjä, T. and Kulmala, M. and Vogel, A. L. and Hoffmann, T. and Ebben, C. J. and Geiger, F. M. and Chhabra, P. and Seinfeld, J. H. and Worsnop, D. R. and Song, W. and Auld, J. and Williams, J. (2013) Biogenic and biomass burning organic aerosol in a boreal forest at Hyytiälä, Finland, during HUMPPA-COPEC 2010. Atmospheric Chemistry and Physics, 13 (24). pp. 12233-12256. ISSN 1680-7316. https://resolver.caltech.edu/CaltechAUTHORS:20140213-094604820

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Abstract

Submicron aerosol particles were collected during July and August 2010 in Hyytiälä, Finland, to determine the composition and sources of aerosol at that boreal forest site. Submicron particles were collected on Teflon filters and analyzed by Fourier transform infrared (FTIR) spectroscopy for organic functional groups (OFGs). Positive matrix factorization (PMF) was applied to aerosol mass spectrometry (AMS) measurements and FTIR spectra to identify summertime sources of submicron aerosol mass at the sampling site. The two largest sources of organic mass (OM) in particles identified at Hyytiälä were (1) biogenic aerosol from surrounding local forest and (2) biomass burning aerosol, transported 4–5 days from large wildfires burning near Moscow, Russia, and northern Ukraine. The robustness of this apportionment is supported by the agreement of two independent analytical methods for organic measurements with three statistical techniques. FTIR factor analysis was more sensitive to the chemical differences between biogenic and biomass burning organic components, while AMS factor analysis had a higher time resolution that more clearly linked the temporal behavior of separate OM factors to that of different source tracers even though their fragment mass spectrum were similar. The greater chemical sensitivity of the FTIR is attributed to the nondestructive preparation and the functional group specificity of spectroscopy. The FTIR spectra show strong similarities among biogenic and biomass burning factors from different regions as well as with reference OM (namely olive tree burning organic aerosol and α-pinene chamber secondary organic aerosol (SOA)). The biogenic factor correlated strongly with temperature and oxidation products of biogenic volatile organic compounds (BVOCs), included more than half of the oxygenated OFGs (carbonyl groups at 29% and carboxylic acid groups at 22%), and represented 35% of the submicron OM. Compared to previous studies at Hyytiälä, the summertime biogenic OM is 1.5 to 3 times larger than springtime biogenic OM (0.64 μg m^−3 and 0.4 μg m^−3, measured in 2005 and 2007, respectively), even though it contributed only 35% of OM. The biomass burning factor contributed 25% of OM on average and up to 62% of OM during three periods of transported biomass burning emissions: 26–28 July, 29–30 July, and 8–9 August, with OFG consisting mostly of carbonyl (41%) and alcohol (25%) groups. The high summertime terrestrial biogenic OM (1.7 μg m^−3) and the high biomass burning contributions (1.2 μg m^−3) were likely due to the abnormally high temperatures that resulted in both stressed boreal forest conditions with high regional BVOC emissions and numerous wildfires in upwind regions.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.5194/acp-13-12233-2013DOIArticle
http://www.atmos-chem-phys.net/13/12233/2013/acp-13-12233-2013.htmlPublisherArticle
ORCID:
AuthorORCID
Russell, L. M.0000-0002-6108-2375
Seinfeld, J. H.0000-0003-1344-4068
Worsnop, D. R.0000-0002-8928-8017
Additional Information:© 2013 Author(s). This work is distributed under the Creative Commons Attribution 3.0 License. Published by Copernicus Publications on behalf of the European Geosciences Union. Received: 23 May 2013; Published in Atmos. Chem. Phys. Discuss.: 15 June 2013; Revised: 1 November 2013; Accepted: 12 November 2013; Published: 17 December 2013. The authors acknowledge NSF grant ATM-0904203 for funding. A. L. Corrigan gratefully acknowledges support by the Department of Energy Office of Science Graduate Fellowship Program (DOE SCGF), made possible in part by the American Recovery and Reinvestment Act of 2009 (DE-AC05-06OR23100). HUMPPA-COPEC measurements and analyses were supported by the ERC grant ATMNUCLE (project no. 227463), Academy of Finland Centre of Excellence program (project no. 1118615), the European Integrated project on Aerosol Cloud Climate and Air Quality Interactions EUCAARI (project no. 036833-2), the EUSAAR TNA (project no. 400586), and the IMECC TA (project no. 4006261). We thank the Hyytiälä engineers and staff for support during the campaign, Pasi Aalto for his support with filter equipment and Spyros Pandis for providing biomass burning aerosol samples. Edited by: A. Goldstein.
Funders:
Funding AgencyGrant Number
NSFATM-0904203
Department of Energy (DOE)DE-AC05-06OR23100
European Research Council (ERC)227463
Academy of Finland1118615
European Integrated project on Aerosol Cloud Climate and Air Quality Interactions EUCAARI036833-2
EUSAAR TNA400586
IMECC TA4006261
Issue or Number:24
Record Number:CaltechAUTHORS:20140213-094604820
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140213-094604820
Official Citation:Corrigan, A. L., Russell, L. M., Takahama, S., Äijälä, M., Ehn, M., Junninen, H., Rinne, J., Petäjä, T., Kulmala, M., Vogel, A. L., Hoffmann, T., Ebben, C. J., Geiger, F. M., Chhabra, P., Seinfeld, J. H., Worsnop, D. R., Song, W., Auld, J., and Williams, J.: Biogenic and biomass burning organic aerosol in a boreal forest at Hyytiälä, Finland, during HUMPPA-COPEC 2010, Atmos. Chem. Phys., 13, 12233-12256, doi:10.5194/acp-13-12233-2013, 2013.
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:43806
Collection:CaltechAUTHORS
Deposited By: Jason Perez
Deposited On:14 Feb 2014 00:10
Last Modified:03 Oct 2019 06:11

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