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Geochemical diversity in first rocks examined by the Curiosity Rover in Gale Crater: Evidence for and significance of an alkali and volatile-rich igneous source

Schmidt, M. E. and Grotzinger, J. and Stack, K. and Ehlmann, B. L. and Stolper, E. M. (2014) Geochemical diversity in first rocks examined by the Curiosity Rover in Gale Crater: Evidence for and significance of an alkali and volatile-rich igneous source. Journal of Geophysical Research. Planets, 119 (1). pp. 64-81. ISSN 2169-9097. http://resolver.caltech.edu/CaltechAUTHORS:20140228-082203424

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Abstract

The first four rocks examined by the Mars Science Laboratory Alpha Particle X-ray Spectrometer indicate that Curiosity landed in a lithologically diverse region of Mars. These rocks, collectively dubbed the Bradbury assemblage, were studied along an eastward traverse (sols 46–102). Compositions range from Na- and Al-rich mugearite Jake_Matijevic to Fe-, Mg-, and Zn-rich alkali-rich basalt/hawaiite Bathurst_Inlet and span nearly the entire range in FeO* and MnO of the data sets from previous Martian missions and Martian meteorites. The Bradbury assemblage is also enriched in K and moderately volatile metals (Zn and Ge). These elements do not correlate with Cl or S, suggesting that they are associated with the rocks themselves and not with salt-rich coatings. Three out of the four Bradbury rocks plot along a line in elemental variation diagrams, suggesting mixing between Al-rich and Fe-rich components. ChemCam analyses give insight to their degree of chemical heterogeneity and grain size. Variations in trace elements detected by ChemCam suggest chemical weathering (Li) and concentration in mineral phases (e.g., Rb and Sr in feldspars). We interpret the Bradbury assemblage to be broadly volcanic and/or volcaniclastic, derived either from near the Gale crater rim and transported by the Peace Vallis fan network, or from a local volcanic source within Gale Crater. High Fe and Fe/Mn in Et_Then likely reflect secondary precipitation of Fe^(3+) oxides as a cement or rind. The K-rich signature of the Bradbury assemblage, if igneous in origin, may have formed by small degrees of partial melting of metasomatized mantle.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1002/2013JE004481DOIArticle
http://onlinelibrary.wiley.com/doi/10.1002/2013JE004481/abstractPublisherArticle
ORCID:
AuthorORCID
Grotzinger, J.0000-0001-9324-1257
Ehlmann, B. L.0000-0002-2745-3240
Stolper, E. M.0000-0001-8008-8804
Additional Information:© 2013 The Authors. This is an open access article under the terms of the Creative Commons Attribution-Non Commercial-No Derivatives License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made. Issue online: 28 February 2014; Version of record online: 16 January 2014; Accepted manuscript online: 9 December 2013; Manuscript Accepted: 3 December 2013; Manuscript Revised: 27 November 2013; Manuscript Received: 9 July 2013. This work was funded by the Canadian Space Agency (CSA) support for the APXS instrument and Participating Scientist grant to Schmidt, and by the NASA MSL mission. Thoughtful reviews by Brian Balta, Cerena Goodrich, and Christian Schrader improved the manuscript. We sincerely thank the many engineers and scientists who have contributed to the great success of the MSL mission.
Funders:
Funding AgencyGrant Number
Canadian Space Agency (CSA)UNSPECIFIED
NASAUNSPECIFIED
Subject Keywords:Mars geochemistry; Mars Science Laboratory; APXS; Gale Crater
Record Number:CaltechAUTHORS:20140228-082203424
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20140228-082203424
Official Citation:Schmidt,M. E., et al. (2014), Geochemical diversity in first rocks examined by the Curiosity Rover in Gale Crater: Evidence for and significance of an alkali and volatile-rich igneous source, J. Geophys. Res. Planets, 119, doi:10.1002/2013JE004481
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:44047
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:28 Feb 2014 16:37
Last Modified:09 Dec 2016 05:08

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