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Spectroscopic Standard for Tetrahedrally Coordinated Ferric Iron: γ LiAIO_2:Fe^(3+)

Waychunas, Glenn A. and Rossman, George R. (1983) Spectroscopic Standard for Tetrahedrally Coordinated Ferric Iron: γ LiAIO_2:Fe^(3+). Physics and Chemistry of Minerals, 9 (5). pp. 212-215. ISSN 0342-1791. https://resolver.caltech.edu/CaltechAUTHORS:20140305-144207545

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Abstract

γ LiAlO_2 doped with Fe^(3+) in the tetrahedral site has been examined by extended X-ray absorption fine structure (EXAFS) analysis, and Mössbauer and optical spectroscopy. The isomer shift (IS) is −0.026 mm/s (Fe-Pd); the quadrupole splitting (QS) is 0.62 mm/s. Anisotropic optical absorption is prominent at ∼391, 452, and 463 nm. The K-edge absorption spectrum shows a prominent absorption near 7,113 ev typical of tetrahedrally coordinated Fe^(3+).


Item Type:Article
Related URLs:
URLURL TypeDescription
http://link.springer.com/article/10.1007%2FBF00311957PublisherArticle
http://dx.doi.org/10.1007/BF00311957DOIArticle
ORCID:
AuthorORCID
Rossman, George R.0000-0002-4571-6884
Additional Information:© 1983 Springer-Verlag. Received October 5, 1982. The X-ray absorption data were collected at the Stanford Synchrotron Radiation Laboratory which is supported by the National Science Foundation through the Division of Materials Research and the National Institutes of Health through the Biotechnology Resource Program in the Division of Research Resources. They LiAl0_2 : Fe^(3+) crystals were synthesized and Mössbauer spectra obtained at UCLA during the Ph.D. dissertation work of one of the authors (G.A. Waychunas). Support from W.A. Dollase (NSF grant DES 74-19918) during this period is gratefully acknowleged. Optical spectroscopy was supported by NSF grant EAR 79-04801.
Funders:
Funding AgencyGrant Number
NSF Division of Materials ResearchUNSPECIFIED
NIH Biotechnology Resource Program in the Division of Research ResourcesUNSPECIFIED
NSFDES 74-19918
NSFEAR 79-04801
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Caltech Division of Geological and Planetary Sciences3812
Issue or Number:5
Record Number:CaltechAUTHORS:20140305-144207545
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140305-144207545
Official Citation: Spectroscopic standard for tetrahedrally coordinated ferric iron: γ LiAlO2:Fe3+ Glenn A. Waychunas, George R. Rossman Pages 212-215
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:44162
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:05 Mar 2014 23:03
Last Modified:26 Nov 2019 11:15

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