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Arene non-innocence in dinuclear complexes of Fe, Co, and Ni supported by a para-terphenyl diphosphine

Horak, Kyle T. and Velian, Alexandra and Day, Michael W. and Agapie, Theodor (2014) Arene non-innocence in dinuclear complexes of Fe, Co, and Ni supported by a para-terphenyl diphosphine. Chemical Communications, 50 (34). pp. 4427-4429. ISSN 1359-7345. https://resolver.caltech.edu/CaltechAUTHORS:20140326-090813158

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Abstract

Cofacial Fe_2, Co_2, and Ni_2 complexes supported by a para-terphenyl diphosphine ligand were prepared. Central arene deplanarization and a μ_2:(η^3,η^3) coordination mode suggest partial bisallyl character in the Fe_2 and Co_2 complexes. An oxidation induced shift in Fe_2–arene binding highlights the non-innocent nature of the arene ligand.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://pubs.rsc.org/en/content/articlelanding/2014/cc/c4cc00838cPublisherArticle
http://dx.doi.org/ 10.1039/C4CC00838CDOIArticle
ORCID:
AuthorORCID
Agapie, Theodor0000-0002-9692-7614
Additional Information:© 2014 Royal Society of Chemistry. Received 30th January 2014, Accepted 28th February 2014. First published online 03 Mar 2014. We thank Lawrence M. Henling for crystallographic assistance. We are grateful to Caltech and NSF CAREER CHE-1151918 for funding. T.A. is a Sloan and Cottrell Fellow. The Bruker X-ray diffractometer was purchased via an NSF CRIF:MU award to Caltech, CHE-0639094.
Funders:
Funding AgencyGrant Number
CaltechUNSPECIFIED
NSF CHE-1151918
NSFCHE-0639094
Issue or Number:34
Record Number:CaltechAUTHORS:20140326-090813158
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140326-090813158
Official Citation:Arene non-innocence in dinuclear complexes of Fe, Co, and Ni supported by a para-terphenyl diphosphine Kyle T. Horak, Alexandra Velian, Michael W. Day and Theodor Agapie Chem. Commun., 2014, Advance Article DOI: 10.1039/C4CC00838C, Communication First published online : 03 Mar 2014
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:44518
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:26 Mar 2014 19:46
Last Modified:03 Oct 2019 06:18

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