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Redox rich dicobalt macrocycles as templates for multi-electron transformations

Szymczak, Nathaniel K. and Berben, Louise A. and Peters, Jonas C. (2009) Redox rich dicobalt macrocycles as templates for multi-electron transformations. Chemical Communications, 2009 (44). pp. 6729-6731. ISSN 1359-7345.

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Pyridazine-templated dicobalt macrocycles reversibly support five oxidation states with unusually positive Co^(II)/Co^I redox couples, and are also active proton reduction electrocatalysts.

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Szymczak, Nathaniel K.0000-0002-1296-1445
Peters, Jonas C.0000-0002-6610-4414
Additional Information:This journal is © The Royal Society of Chemistry 2009. Received 13 Jul 2009, Accepted 17 Sep 2009, First published online 06 Oct 2009. This work was generously supported by BP and an NSF Center for Chemical Innovation grant (Grant CHE-0802907). We thank Dr Yunho Lee and Dr Sebastian Stoian for EPR assistance, and Dr Bruce Brunschwig for helpful discussions. Electronic supplementary information (ESI) available: Complete experimental details and crystal structures. CCDC 740044–740052. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b913946j
Group:CCI Solar Fuels
Funding AgencyGrant Number
NSF Center for Chemical InnovationCHE-0802907
Issue or Number:44
Record Number:CaltechAUTHORS:20140403-151953405
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:44646
Deposited By: George Porter
Deposited On:03 Apr 2014 23:02
Last Modified:09 Mar 2020 13:19

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