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Efficient luminescence from easily prepared three-coordinate copper(I) arylamidophosphines

Lotito, Kenneth J. and Peters, Jonas C. (2010) Efficient luminescence from easily prepared three-coordinate copper(I) arylamidophosphines. Chemical Communications, 46 (21). pp. 3690-3692. ISSN 1359-7345. https://resolver.caltech.edu/CaltechAUTHORS:20140403-160228002

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Abstract

A series of brightly luminescent, three-coordinate copper(I) arylamidophosphine complexes have been prepared from readily available precursors in high yield. Emission maxima span 102 nm in the visible spectrum from 461 (blue) to 563 nm (yellow) while photoluminescence quantum yields range from 0.11 to 0.24 in fluid solution at room temperature.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1039/C000818DDOIArticle
http://pubs.rsc.org/en/content/articlelanding/2010/cc/c000818d#!divAbstractPublisherArticle
http://www.rsc.org/suppdata/cc/c0/c000818d/c000818d.pdfPublisherSupplemental material
http://www.rsc.org/suppdata/cc/c0/c000818d/c000818d.txtPublisherSupplemental material
ORCID:
AuthorORCID
Peters, Jonas C.0000-0002-6610-4414
Additional Information:This journal is © The Royal Society of Chemistry 2010. Received 13th January 2010, Accepted 30th March 2010, First published on the web 14th April 2010. This work was supported by an NSF Center for Chemical Innovation (CHE-0802907). Luminescence measurements were carried out in the laboratory of T. M. Swager with assistance from T. L. Andrews. K. J. L. gratefully acknowledges a fellowship from the MIT Energy Initiative. Electronic supplementary information (ESI) available: Synthetic procedures and characterization, absorption spectrum of 6, excitation and emission spectra, electrochemical data, and solid state structures. CCDC 766167 (1), 766168 (2), 766169 (3), 766170 (7). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c000818d
Group:CCI Solar Fuels
Funders:
Funding AgencyGrant Number
NSF Center for Chemical Innovation CHE-0802907
MIT Energy InitiativeUNSPECIFIED
Other Numbering System:
Other Numbering System NameOther Numbering System ID
CCDC766167
CCDC766168
CCDC766169
CCDC766170
Issue or Number:21
Record Number:CaltechAUTHORS:20140403-160228002
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140403-160228002
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:44651
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:04 Apr 2014 15:05
Last Modified:26 Nov 2019 11:15

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