Takematsu, K. and Williamson, H. and Winkler, J. R. and Gray, H. B. (2014) Intra- and intermolecular electron hopping via tryptophan in azurin. Journal of Biological Inorganic Chemistry, 19 (Supplement1). S231. ISSN 0949-8257. doi:10.1007/s00775-014-1095-8. https://resolver.caltech.edu/CaltechAUTHORS:20140424-153153082
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Abstract
We previously showed that electron transfer (ET) between electronically excited Re (^*RE) and Cu(I)in Re-modified Pseudomonas aeruginosa azurin mutant ReH124W122Cu(I)(Re=4,7-dimethylphenanthrolineRe(CO)3) is facilitated by W122, with hopping occurring over 19 Å in 30 ns, >100x faster than single step electron tunneling.
| Item Type: | Article | |||||||||
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| Additional Information: | © 2014 Springer. CONTROL ID: 1709659 | |||||||||
| Issue or Number: | Supplement1 | |||||||||
| DOI: | 10.1007/s00775-014-1095-8 | |||||||||
| Record Number: | CaltechAUTHORS:20140424-153153082 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20140424-153153082 | |||||||||
| Official Citation: | J Biol Inorg Chem. 2014 Mar;19 Suppl 1:1-696. doi: 10.1007/s00775-014-1095-8. XVI(th) International Conference on Biological Inorganic Chemistry | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 45200 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 24 Apr 2014 22:59 | |||||||||
| Last Modified: | 10 Nov 2021 17:01 |
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