Marcus, R. A. (1952) Lifetimes of Active Molecules. I. Journal of Chemical Physics, 20 (3). pp. 352-354. ISSN 0021-9606. https://resolver.caltech.edu/CaltechAUTHORS:20140429-121818785
|
PDF
- Published Version
See Usage Policy. 219kB |
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20140429-121818785
Abstract
The specific dissociation constants for various vibrationally excited molecules (methane, ethane, and propane) are inferred from an interpretation of experimental data on atomic cracking reactions and on the deuterization of free radicals. As was to be expected, these dissociation constants decrease with increasing number of degrees of freedom of the decomposing molecule.
| Item Type: | Article | ||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Related URLs: |
| ||||||||||||
| ORCID: |
| ||||||||||||
| Additional Information: | © 1952 American Institute of Physics. Received 03 August 1951; Published online 23 December 2004. This work was financially assisted by the Office of Naval Research, Contract No. N8onr-77900. I should like to thank Professor O. K. Rice for reading the manuscript and for making several helpful suggestions. | ||||||||||||
| Funders: |
| ||||||||||||
| Subject Keywords: | Molecular dissociation; Atom reactions; Cracks; Free radical reactions; Methane | ||||||||||||
| Issue or Number: | 3 | ||||||||||||
| Record Number: | CaltechAUTHORS:20140429-121818785 | ||||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20140429-121818785 | ||||||||||||
| Official Citation: | Marcus, R. A. (1952). Lifetimes of Active Molecules. I. The Journal of Chemical Physics, 20(3), 352-354. doi: doi:http://dx.doi.org/10.1063/1.1700422 | ||||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
| ID Code: | 45304 | ||||||||||||
| Collection: | CaltechAUTHORS | ||||||||||||
| Deposited By: | Aucoeur Ngo | ||||||||||||
| Deposited On: | 29 Apr 2014 19:52 | ||||||||||||
| Last Modified: | 22 Nov 2019 09:58 |
Repository Staff Only: item control page
