Baricuatro, Jack H. and Kim, Youn-Geun and Saadi, Fadl H. and McCrory, Charles C. L. and Sanabria-Chinchilla, Jean and Crouthers, Danielle and Darensbourg, Marcetta Y. and Soriaga, Manuel P. (2014) Heterogenization of a Water-Insoluble Molecular Complex for Catalysis of the Proton-Reduction Reaction in Highly Acidic Aqueous Solutions. Electrocatalysis, 5 (3). pp. 226-228. ISSN 1868-2529. doi:10.1007/s12678-014-0200-7. https://resolver.caltech.edu/CaltechAUTHORS:20140505-132735594
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Abstract
Our long-held interest in the resiliency of electrochemical functionalities upon surface immobilization has herded us from directly chemisorbed electroactive moieties, to anchor group-leashed redox-active couples and to surface-tethered enzyme-inspired molecular catalysts. The latter represent the most intricate because the electrocatalytic activities involve mixed-valence states and may require certain entatic (fractionally rotated) configurations. In this regard, we recently investigated the proton-reduction electrocatalysis by hydrogenase-inspired di-iron complexes at polycrystalline and (111)-faceted Au electrodes.
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Additional Information: | © 2014 Springer Science+Business Media New York. Published online: 26 April 2014. This material is based upon work performed by the Joint Center for Artificial Photosynthesis, a DOE Energy Innovation Hub, as follows: except for the synthesis of the di-iron complexes which was funded by the National Science Foundation (CHE-091679 and CHE-1266097) (MYD), all the work was supported through the Office of Science of the US Department of Energy under Award No. DE-SC0004993. | ||||||||||||
Group: | JCAP | ||||||||||||
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Issue or Number: | 3 | ||||||||||||
DOI: | 10.1007/s12678-014-0200-7 | ||||||||||||
Record Number: | CaltechAUTHORS:20140505-132735594 | ||||||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20140505-132735594 | ||||||||||||
Official Citation: | Baricuatro, J.H., Kim, YG., Saadi, F.H. et al. Electrocatalysis (2014) 5: 226. doi:10.1007/s12678-014-0200-7 | ||||||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
ID Code: | 45500 | ||||||||||||
Collection: | CaltechAUTHORS | ||||||||||||
Deposited By: | INVALID USER | ||||||||||||
Deposited On: | 05 May 2014 21:27 | ||||||||||||
Last Modified: | 10 Nov 2021 17:04 |
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