Donohue, Jerry and Schomaker, Verner (1948) The Molecular Structure of Dimethyltrisulfide, (CH_3)_2S_3. Journal of Chemical Physics, 16 (2). pp. 92-96. ISSN 0021-9606. doi:10.1063/1.1746822. https://resolver.caltech.edu/CaltechAUTHORS:20140506-091635695
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Abstract
Dimethyltrisulfide (CH_3)_2S_3 has been investigated by the electron diffraction method. The molecule was found to have the chain configuration, with the following interatomic distances and angles: C-H=1.09A (assumed), C-S=1.78±0.04A, S-S=2.04A, ±0.02A, ∠H-C-S=112° (assumed), ∠S-S-S=104°±5°, and ∠C-S-S=104°±5°. The results also suggest that the C-S bonds oscillate with rather large amplitude about a mean position approximately 106° out of the plane of the three sulfur atoms.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1948 American Institute of Physics. Received July 1, 1947. The work herein was done under Contract OEMsr-753 between the National Defense Research Committee and the California Institute of Technology. Contribution No. 1108 from the Gates and Crellin Laboratories of Chemistry, California Institute of Technology. | |||||||||
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| Subject Keywords: | Chemical bonds; Electron diffraction; Interatomic distances; Molecular structure | |||||||||
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| Issue or Number: | 2 | |||||||||
| DOI: | 10.1063/1.1746822 | |||||||||
| Record Number: | CaltechAUTHORS:20140506-091635695 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20140506-091635695 | |||||||||
| Official Citation: | Donohue, J., & Schomaker, V. (1948). The Molecular Structure of Dimethyltrisulfide, (CH3)2S3. The Journal of Chemical Physics, 16(2), 92-96. doi: doi:http://dx.doi.org/10.1063/1.1746822 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 45516 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | INVALID USER | |||||||||
| Deposited On: | 06 May 2014 17:16 | |||||||||
| Last Modified: | 10 Nov 2021 17:04 |
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