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The Infra-Red Spectrum and Molecular Configuration of Hydrogen Persulfide

Wilson, M. Kent and Badger, Richard M. (1949) The Infra-Red Spectrum and Molecular Configuration of Hydrogen Persulfide. Journal of Chemical Physics, 17 (12). pp. 1232-1236. ISSN 0021-9606. https://resolver.caltech.edu/CaltechAUTHORS:20140506-121846518

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Abstract

The infra‐red spectrum of hydrogen persulfide has been investigated in the region 1.5 to 15μ, and vibrational assignments have been made. The perpendicular band at 2μ has been studied under high resolution and a value for one of the rotational constants has been obtained. The data strongly support a chain structure for hydrogen persulfide and probably exclude cis- or trans-planar structures, but give no very definite information regarding the azimuthal angle.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1063/1.1747148DOIArticle
http://scitation.aip.org/content/aip/journal/jcp/17/12/10.1063/1.1747148PublisherArticle
Additional Information:© 1949 American Institute of Physics. Received March 25, 1949. Contribution No. 1264 from the Gates and Crellin Laboratories of Chemistry.
Subject Keywords:Molecular spectra; Molecular configuration; Rotation constants
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Caltech Gates and Crellin Laboratories of Chemistry1264
Issue or Number:12
Record Number:CaltechAUTHORS:20140506-121846518
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140506-121846518
Official Citation:Wilson, M. K., & Badger, R. M. (1949). The Infra‐Red Spectrum and Molecular Configuration of Hydrogen Persulfide. The Journal of Chemical Physics, 17(12), 1232-1236. doi: doi:http://dx.doi.org/10.1063/1.1747148
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:45528
Collection:CaltechAUTHORS
Deposited By: Aucoeur Ngo
Deposited On:06 May 2014 20:08
Last Modified:03 Oct 2019 06:32

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