Whittaker, A. Greenville and Yost, Don M. (1949) Magnetic Susceptibility, Freezing Point Diagram, Density, and Spectral Absorption of the System Vanadium Tetrachloride-Carbon Tetrachloride. Journal of Chemical Physics, 17 (2). pp. 188-195. ISSN 0021-9606. doi:10.1063/1.1747210. https://resolver.caltech.edu/CaltechAUTHORS:20140506-123141717
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Abstract
On the basis of results of freezing point lowering experiments, it was reported by Simons and Powell that an equilibrium existed between VCl_4, and V_2Cl_8 in carbon tetrachloride solution. Since vanadium tetrachloride is an odd molecule, it was implied that dimerization could take place, as in nitrogen dioxide, such that the odd electrons become paired. In the present paper are reported the results of a study on the system by means of magnetic susceptibility measurements, freezing point diagram determination, and spectral absorption of the solution, as a function of concentration of vanadium tetrachloride in carbon tetrachloride.
| Item Type: | Article | |||||||||
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| Additional Information: | ©1949 American Institute of Physics. We wish to thank Professors V. Schomaker, R. Badger, and J. Hildebrand, and Dr. O. Wulf for many helpful discussions and suggestions. We are also very grateful to the Research Corporation for a grant which aided, in part, the work reported here. Our good friend, Mr. Hal Weis, gave us much valuable technical assistance. | |||||||||
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| Subject Keywords: | Absorption spectra; Magnetic susceptibilities; Vanadium | |||||||||
| Issue or Number: | 2 | |||||||||
| DOI: | 10.1063/1.1747210 | |||||||||
| Record Number: | CaltechAUTHORS:20140506-123141717 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20140506-123141717 | |||||||||
| Official Citation: | Whittaker, A. G., & Yost, D. M. (1949). Magnetic Susceptibility, Freezing Point Diagram, Density, and Spectral Absorption of the System Vanadium Tetrachloride‐Carbon Tetrachloride. The Journal of Chemical Physics, 17(2), 188-195. doi: http://dx.doi.org/10.1063/1.1747210 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 45529 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | INVALID USER | |||||||||
| Deposited On: | 06 May 2014 20:12 | |||||||||
| Last Modified: | 10 Nov 2021 17:13 |
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