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Organic aerosol formation from the reactive uptake of isoprene epoxydiols (IEPOX) onto non-acidified inorganic seeds

Nguyen, T. B. and Coggon, M. M. and Bates, K. H. and Zhang, X. and Schwantes, R. H. and Schilling, K. A. and Loza, C. L. and Flagan, R. C. and Wennberg, P. O. and Seinfeld, J. H. (2014) Organic aerosol formation from the reactive uptake of isoprene epoxydiols (IEPOX) onto non-acidified inorganic seeds. Atmospheric Chemistry and Physics, 14 (7). pp. 3497-3510. ISSN 1680-7316. doi:10.5194/acp-14-3497-2014.

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The reactive partitioning of cis and trans β-IEPOX was investigated on hydrated inorganic seed particles, without the addition of acids. No organic aerosol (OA) formation was observed on dry ammonium sulfate (AS); however, prompt and efficient OA growth was observed for the cis and trans β-IEPOX on AS seeds at liquid water contents of 40–75% of the total particle mass. OA formation from IEPOX is a kinetically limited process, thus the OA growth continues if there is a reservoir of gas-phase IEPOX. There appears to be no differences, within error, in the OA growth or composition attributable to the cis / trans isomeric structures. Reactive uptake of IEPOX onto hydrated AS seeds with added base (NaOH) also produced high OA loadings, suggesting the pH dependence for OA formation from IEPOX is weak for AS particles. No OA formation, after particle drying, was observed on seed particles where Na^+ was substituted for NH^(+)_(4). The Henry's Law partitioning of IEPOX was measured on NaCl particles (ionic strength ~9 M) to be 3 × 10^7 M atm^−1 (−50 / +100%). A small quantity of OA was produced when NH4+ was present in the particles, but the chloride (Cl-) anion was substituted for sulfate (SO^(2-)_(4)), possibly suggesting differences in nucleophilic strength of the anions. Online time-of-flight aerosol mass spectrometry and offline filter analysis provide evidence of oxygenated hydrocarbons, organosulfates, and amines in the particle organic composition. The results are consistent with weak correlations between IEPOX-derived OA and particle acidity or liquid water observed in field studies, as the chemical system is nucleophile-limited and not limited in water or catalyst activity.

Item Type:Article
Related URLs:
URLURL TypeDescription
Coggon, M. M.0000-0002-5763-1925
Bates, K. H.0000-0001-7544-9580
Schwantes, R. H.0000-0002-7095-3718
Flagan, R. C.0000-0001-5690-770X
Wennberg, P. O.0000-0002-6126-3854
Seinfeld, J. H.0000-0003-1344-4068
Additional Information:© 2014 Author(s). This work is distributed under the Creative Commons Attribution 3.0 License. Received: 10 October 2013; Published in Atmos. Chem. Phys. Discuss.: 28 October 2013; Revised: 8 February 2014; Accepted: 18 February 2014; Published: 8 April 2014. This research was supported by the National Science Foundation (NSF) grants AGS-1057183 and AGS-1240604. TBN acknowledges funding from the NSF Postdoctoral Research Fellowship program, award AGS-1331360, and from the Foster and Coco Stanback Postdoctoral Fellowship. We are grateful for research support provided by the Brian Stoltz Group at Caltech for the syntheses of the β-IEPOX isomers, with special acknowledgement to Dr. Nathan Bennett. We thank Dr. Nathan Dalleska, director of the Caltech Environmental Analysis Center (EAC), for his assistance with the UPLC/ESI-ToFMS analyses.
Funding AgencyGrant Number
NSFAGS- 1240604
NSF Postdoctoral FellowshipAGS-1331360
Foster and Coco Stanback Postdoctoral FellowshipUNSPECIFIED
Issue or Number:7
Record Number:CaltechAUTHORS:20140529-084758310
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Official Citation:Nguyen, T. B., Coggon, M. M., Bates, K. H., Zhang, X., Schwantes, R. H., Schilling, K. A., Loza, C. L., Flagan, R. C., Wennberg, P. O., and Seinfeld, J. H.: Organic aerosol formation from the reactive uptake of isoprene epoxydiols (IEPOX) onto non-acidified inorganic seeds, Atmos. Chem. Phys., 14, 3497-3510, doi:10.5194/acp-14-3497-2014, 2014.
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:45958
Deposited By: Jason Perez
Deposited On:29 May 2014 19:52
Last Modified:10 Nov 2021 17:18

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