Liu, Albert Tianxiang and Zaveri, Rahul A. and Seinfeld, John H. (2014) Analytical solution for transient partitioning and reaction of a condensing vapor species in a droplet. Atmospheric Environment, 89 . pp. 651-654. ISSN 1352-2310. https://resolver.caltech.edu/CaltechAUTHORS:20140605-084912235
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Abstract
We present the exact analytical solution of the transient equation of gas-phase diffusion of a condensing vapor to, and diffusion and reaction in, an aqueous droplet. Droplet-phase reaction is represented by first-order chemistry. The solution facilitates study of the dynamic nature of the vapor uptake process as a function of droplet size, Henry's law coefficient, and first-order reaction rate constant for conversion in the droplet phase.
Item Type: | Article | |||||||||
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Additional Information: | © 2014 Elsevier Ltd. Received 11 December 2013; Received in revised form 25 February 2014; Accepted 28 February 2014; Available online 1 March 2014. Participation of RAZ in this study was supported by the US Department of Energy (DOE) Atmospheric System Research (ASR) Program under contract DE-AC06-76RLO 1830 at Pacific Northwest National Laboratory. | |||||||||
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Subject Keywords: | Droplet; Diffusion and reaction; Henry's law constant | |||||||||
Record Number: | CaltechAUTHORS:20140605-084912235 | |||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20140605-084912235 | |||||||||
Official Citation: | Albert Tianxiang Liu, Rahul A. Zaveri, John H. Seinfeld, Analytical solution for transient partitioning and reaction of a condensing vapor species in a droplet, Atmospheric Environment, Volume 89, June 2014, Pages 651-654, ISSN 1352-2310, http://dx.doi.org/10.1016/j.atmosenv.2014.02.065. (http://www.sciencedirect.com/science/article/pii/S1352231014001617) | |||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
ID Code: | 46088 | |||||||||
Collection: | CaltechAUTHORS | |||||||||
Deposited By: | Tony Diaz | |||||||||
Deposited On: | 05 Jun 2014 16:25 | |||||||||
Last Modified: | 09 Mar 2020 13:19 |
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