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Measurement of gas-phase hydroperoxides by chemical ionization mass spectrometry

Crounse, John D. and McKinney, Karena A. and Kwan, Alan J. and Wennberg, Paul O. (2006) Measurement of gas-phase hydroperoxides by chemical ionization mass spectrometry. Analytical Chemistry, 78 (19). pp. 6726-6732. ISSN 0003-2700. https://resolver.caltech.edu/CaltechAUTHORS:20140702-114950015

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Abstract

A new method for the detection of gas-phase hydroperoxides is described. The clustering chemistry of CF_(3)O^(-) is exploited to produce speciated measurements of several hydroperoxides with high sensitivity and fast time response. Correspondence of airborne observations made with this technique and the established HPLC method is illustrated. CF_(3)O^(-) appears to be a highly versatile reagent ion for measurements of both weak and strong acids in the atmosphere.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ac0604235DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ac0604235PublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/ac0604235PublisherSupporting Information
ORCID:
AuthorORCID
Crounse, John D.0000-0001-5443-729X
McKinney, Karena A.0000-0003-1129-1678
Wennberg, Paul O.0000-0002-6126-3854
Additional Information:© 2006 American Chemical Society. Received for review March 8, 2006. Accepted June 28, 2006. We thank Dan O’Sullivan, Julie Snow, Haiwei Shen, and Brian Heikes for allowing us to show their H_(2)O_(2) and PAA data prior to publication. We thank Norton Allen and James Oliver for their assistance in the preparation of the CIMS instrument for the DC-8. We thank Suresh Dhaniyala for his assistance in the design of the inlet. Funding for this work was provided by a grant from the National Aeronautics and Space Administration (NAG: NNG04- GA59G). J.D.C. and A.J.K. thank the EPA-STAR Fellowship Program (FP916334012) and the NSF Graduate Research Fellowship program, respectively, for providing support. This work has not been formally reviewed by the EPA. The views expressed in this document are solely those of the authors and the EPA does not endorse any products or commercial services mentioned in this publication.
Funders:
Funding AgencyGrant Number
NASANNG04-GA59G
Environmental Protection Agency (EPA)FP916334012
NSF Graduate Research FellowshipUNSPECIFIED
Issue or Number:19
Record Number:CaltechAUTHORS:20140702-114950015
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140702-114950015
Official Citation:Crounse, J. D., McKinney, K. A., Kwan, A. J., and Wennberg, P. O. (2006). Measurement of Gas-Phase Hydroperoxides by Chemical Ionization Mass Spectrometry. Analytical Chemistry, 78(19), 6726-6732. doi: 10.1021/ac0604235
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:46638
Collection:CaltechAUTHORS
Deposited By: Joanne McCole
Deposited On:02 Jul 2014 22:20
Last Modified:09 Mar 2020 13:19

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