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Synthesis and characterization of conjugated polymers containing first row transition metal complexes

Yuan, Shengwen and Jaramillo, R. and Rosenbaum, T. F. and Yu, Luping (2006) Synthesis and characterization of conjugated polymers containing first row transition metal complexes. Macromolecules, 39 (25). pp. 8652-8658. ISSN 0024-9297. doi:10.1021/ma061447g. https://resolver.caltech.edu/CaltechAUTHORS:20140707-163027812

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Abstract

A series of novel conjugated polymers containing first row transition metal complexes have been synthesized and characterized. Metal complexes including Mn(II), Fe(II), Co(II), Ni(II), and Cu(II) were incorporated into the bipyridine coordination sites of the conjugated polymer backbone. Upon inclusion of the metal complexes the absorption bands of the polymers were red-shifted and metal-to-ligand charge transfer (MLCT) bands were observed. The magnetic properties of these polymers were studied and the results showed that they all had high paramagnetic susceptibility; where applicable they were all stable in the high-spin state. Their large free spins and stability makes them promising as magnetic materials.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ma061447gDOIArticle
http://pubs.acs.org/doi/abs/10.1021/ma061447gPublisherArticle
Additional Information:Copyright © 2006 American Chemical Society. Published In Issue December 12, 2006. Received June 27, 2006; Revised Manuscript Received September 27, 2006. This work was supported by the NSF Materials Research Science and Engineering Center Grant DMR-0213745. R.J. gratefully acknowledges the support of a National Science Foundation Graduate Research Fellowship.
Funders:
Funding AgencyGrant Number
NSFDMR-0213745
NSF Graduate Research FellowshipUNSPECIFIED
Issue or Number:25
DOI:10.1021/ma061447g
Record Number:CaltechAUTHORS:20140707-163027812
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140707-163027812
Official Citation:Synthesis and Characterization of Conjugated Polymers Containing First Row Transition Metal Complexes Shengwen Yuan, R. Jaramillo, T. F. Rosenbaum, and, and Luping Yu Macromolecules 2006 39 (25), 8652-8658
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:46947
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:09 Jul 2014 15:15
Last Modified:10 Nov 2021 17:31

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