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Benzene C−H Activation at a Charge Neutral Zwitterionic Platinum(II) Complex

Thomas, J. Christopher and Peters, Jonas C. (2001) Benzene C−H Activation at a Charge Neutral Zwitterionic Platinum(II) Complex. Journal of the American Chemical Society, 123 (21). pp. 5100-5101. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20140722-093726094

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Abstract

Cationic, coordinatively unsaturated metal centers exhibit a wide range of both stoichiometric and catalytic transformations. Such species are frequently generated by methide abstraction with a strong Lewis acid, or alternatively by protonation with an acid whose conjugate base is noncoordinating or weakly coordinating.3 We are targeting charge neutral, zwitterionic complexes that display reaction chemistry reminiscent of these reactive metal centers. Of particular interest is the development of species that exhibit transformations at X-H bonds, where an X-H bond refers generally to a C-H or other robust σ bond. A conceptual diagram illustrating this strategy is shown in Scheme 1.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja0058987 DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja0058987PublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/ja0058987PublisherSupporting Information
ORCID:
AuthorORCID
Peters, Jonas C.0000-0002-6610-4414
Additional Information:© 2001 American Chemical Society. Received December 18, 2000. Publication Date (Web): May 5, 2001. We thank the California Institute of Technology for its generous support of this research through a start-up grant. J.C.P. thanks the Dreyfus Foundation for a Dreyfus New Faculty Award. J.C.T. thanks the National Science Foundation and the California Institute of Technology for financial support. The authors thank Prof. John Bercaw for helpful discussions and Dr. Michael Day and Lawrence Henling for their assistance with X-ray crystallography.
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CaltechUNSPECIFIED
Camille and Henry Dreyfus FoundationUNSPECIFIED
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Issue or Number:21
Record Number:CaltechAUTHORS:20140722-093726094
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140722-093726094
Official Citation:Benzene C−H Activation at a Charge Neutral Zwitterionic Platinum(II) Complex J. Christopher Thomas and and Jonas C. Peters Journal of the American Chemical Society 2001 123 (21), 5100-5101
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:47387
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:22 Jul 2014 16:53
Last Modified:26 Nov 2019 11:15

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