Qian, Baixin and Henling, Lawrence M. and Peters, Jonas C. (2000) Synthesis and Structure of Li[(C_5H_4)CH_2CH_2(TACN-^iPr_2)]. A Lithium Complex Supported by a Cp/TACN-^iPr_2 Ligand. Organometallics, 19 (14). pp. 2805-2808. ISSN 0276-7333. http://resolver.caltech.edu/CaltechAUTHORS:20140722-095258009
|
PDF
- Supplemental Material
See Usage Policy. 967Kb |
Use this Persistent URL to link to this item: http://resolver.caltech.edu/CaltechAUTHORS:20140722-095258009
Abstract
The new ligand (C_5H_5)CH_2CH_2(TACN-^iPr_2) (TACN-^iPr_2 = 4,7-diisopropyl-1,4,7-triaza-1-cyclononyl) has been prepared and structurally characterized as its lithium complex, Li[(C_5H_4)CH_2CH_2(TACN-^iPr_2)]. The method of preparation employed nucleophilic addition of the lithium amide complex [Li(TACN-^iPr_2)]_2 to spiro[2.4]hepta-4,6-diene. The crystal structure of [Li(TACN-^iPr_2)]_2 is also presented.
| Item Type: | Article | ||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Related URLs: |
| ||||||||||||
| Additional Information: | © 2000 American Chemical Society. Received February 15, 2000; Publication on Web 05/31/2000. We wish to thank the California Institute of Technology for its generous support of this research through a start-up grant. We would like to express our thanks to Professor John Arnold for discussing related results with us prior to publication. Finally, Mr. Matthew Allen is acknowledged for his assistance with the preparation of TACN-^iPr_2. | ||||||||||||
| Funders: |
| ||||||||||||
| Record Number: | CaltechAUTHORS:20140722-095258009 | ||||||||||||
| Persistent URL: | http://resolver.caltech.edu/CaltechAUTHORS:20140722-095258009 | ||||||||||||
| Official Citation: | Qian, B., Henling, L. M., & Peters, J. C. (2000). Synthesis and Structure of Li[(C_5H_4)CH_2CH_2(TACN-^iPr_2)]. A Lithium Complex Supported by a Cp/TACN-^iPr_2 Ligand. Organometallics, 19(14), 2805-2808. doi: 10.1021/om000147z | ||||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
| ID Code: | 47389 | ||||||||||||
| Collection: | CaltechAUTHORS | ||||||||||||
| Deposited By: | Joanne McCole | ||||||||||||
| Deposited On: | 22 Jul 2014 19:51 | ||||||||||||
| Last Modified: | 22 Jul 2014 19:51 |
Repository Staff Only: item control page
