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Synthesis and Structure of Li[(C_5H_4)CH_2CH_2(TACN-^iPr_2)]. A Lithium Complex Supported by a Cp/TACN-^iPr_2 Ligand

Qian, Baixin and Henling, Lawrence M. and Peters, Jonas C. (2000) Synthesis and Structure of Li[(C_5H_4)CH_2CH_2(TACN-^iPr_2)]. A Lithium Complex Supported by a Cp/TACN-^iPr_2 Ligand. Organometallics, 19 (14). pp. 2805-2808. ISSN 0276-7333. http://resolver.caltech.edu/CaltechAUTHORS:20140722-095258009

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Abstract

The new ligand (C_5H_5)CH_2CH_2(TACN-^iPr_2) (TACN-^iPr_2 = 4,7-diisopropyl-1,4,7-triaza-1-cyclononyl) has been prepared and structurally characterized as its lithium complex, Li[(C_5H_4)CH_2CH_2(TACN-^iPr_2)]. The method of preparation employed nucleophilic addition of the lithium amide complex [Li(TACN-^iPr_2)]_2 to spiro[2.4]hepta-4,6-diene. The crystal structure of [Li(TACN-^iPr_2)]_2 is also presented.


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http://dx.doi.org/10.1021/om000147zDOIArticle
http://pubs.acs.org/doi/abs/10.1021/om000147zPublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/om000147zPublisherSupporting Information
Additional Information:© 2000 American Chemical Society. Received February 15, 2000; Publication on Web 05/31/2000. We wish to thank the California Institute of Technology for its generous support of this research through a start-up grant. We would like to express our thanks to Professor John Arnold for discussing related results with us prior to publication. Finally, Mr. Matthew Allen is acknowledged for his assistance with the preparation of TACN-^iPr_2.
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Record Number:CaltechAUTHORS:20140722-095258009
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20140722-095258009
Official Citation:Qian, B., Henling, L. M., & Peters, J. C. (2000). Synthesis and Structure of Li[(C_5H_4)CH_2CH_2(TACN-^iPr_2)]. A Lithium Complex Supported by a Cp/TACN-^iPr_2 Ligand. Organometallics, 19(14), 2805-2808. doi: 10.1021/om000147z
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:47389
Collection:CaltechAUTHORS
Deposited By: Joanne McCole
Deposited On:22 Jul 2014 19:51
Last Modified:22 Jul 2014 19:51

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