Synthesis and Structure of Li[(C_5H_4)CH_2CH_2(TACN-^iPr_2)]. A Lithium Complex Supported by a Cp/TACN-^iPr_2 Ligand

Qian, Baixin and Henling, Lawrence M. and Peters, Jonas C. (2000) Synthesis and Structure of Li[(C_5H_4)CH_2CH_2(TACN-^iPr_2)]. A Lithium Complex Supported by a Cp/TACN-^iPr_2 Ligand. Organometallics, 19 (14). pp. 2805-2808. ISSN 0276-7333. doi:10.1021/om000147z. https://resolver.caltech.edu/CaltechAUTHORS:20140722-095258009

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Abstract

The new ligand (C_5H_5)CH_2CH_2(TACN-^iPr_2) (TACN-^iPr_2 = 4,7-diisopropyl-1,4,7-triaza-1-cyclononyl) has been prepared and structurally characterized as its lithium complex, Li[(C_5H_4)CH_2CH_2(TACN-^iPr_2)]. The method of preparation employed nucleophilic addition of the lithium amide complex [Li(TACN-^iPr_2)]_2 to spiro[2.4]hepta-4,6-diene. The crystal structure of [Li(TACN-^iPr_2)]_2 is also presented.

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Article

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URL	URL Type	Description
http://dx.doi.org/10.1021/om000147z	DOI	Article
http://pubs.acs.org/doi/abs/10.1021/om000147z	Publisher	Article
http://pubs.acs.org/doi/suppl/10.1021/om000147z	Publisher	Supporting Information

ORCID:

Author	ORCID
Peters, Jonas C.	0000-0002-6610-4414

Additional Information:

© 2000 American Chemical Society. Received February 15, 2000; Publication on Web 05/31/2000. We wish to thank the California Institute of Technology for its generous support of this research through a start-up grant. We would like to express our thanks to Professor John Arnold for discussing related results with us prior to publication. Finally, Mr. Matthew Allen is acknowledged for his assistance with the preparation of TACN-^iPr_2.

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Funding Agency	Grant Number
Caltech	UNSPECIFIED

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DOI:

10.1021/om000147z

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CaltechAUTHORS:20140722-095258009

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https://resolver.caltech.edu/CaltechAUTHORS:20140722-095258009

Official Citation:

Qian, B., Henling, L. M., & Peters, J. C. (2000). Synthesis and Structure of Li[(C_5H_4)CH_2CH_2(TACN-^iPr_2)]. A Lithium Complex Supported by a Cp/TACN-^iPr_2 Ligand. Organometallics, 19(14), 2805-2808. doi: 10.1021/om000147z

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47389

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Deposited On:

22 Jul 2014 19:51

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10 Nov 2021 17:39

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