Thomas, Christine M. and Peters, Jonas C. (2004) Coordinating Anions: (Phosphino)tetraphenylborate Ligands as New Reagents for Synthesis. Inorganic Chemistry, 43 (1). pp. 8-10. ISSN 0020-1669. doi:10.1021/ic0350234. https://resolver.caltech.edu/CaltechAUTHORS:20140722-104615116
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Abstract
Anionic, electron-releasing phosphines that incorporate a borate counteranion within the ligand framework are promising reagents for organometallic catalysis. This report describes the synthesis of a new class of monodentate tertiary phosphines built upon the commonly employed tetraphenylborate anion. These new phosphines are highly stable and strongly electron-releasing and readily coordinate transition metals. Moreover, they are promising reagents for catalysis, as demonstrated by their ability to promote the Suzuki cross-coupling of aryl chloride substrates.
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Additional Information: | © 2004 American Chemical Society. Received August 31, 2003. The NSF (CHE-01232216) and BP have provided financial support for this work. Larry Henling and J. Christopher Thomas provided assistance with the crystallographic studies. | ||||||||||||
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Issue or Number: | 1 | ||||||||||||
DOI: | 10.1021/ic0350234 | ||||||||||||
Record Number: | CaltechAUTHORS:20140722-104615116 | ||||||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20140722-104615116 | ||||||||||||
Official Citation: | Coordinating Anions: (Phosphino)tetraphenylborate Ligands as New Reagents for Synthesis Christine M. Thomas and and Jonas C. Peters Inorganic Chemistry 2004 43 (1), 8-10 | ||||||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
ID Code: | 47392 | ||||||||||||
Collection: | CaltechAUTHORS | ||||||||||||
Deposited By: | INVALID USER | ||||||||||||
Deposited On: | 22 Jul 2014 23:06 | ||||||||||||
Last Modified: | 10 Nov 2021 17:39 |
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