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Base-Promoted Benzene C−H Activation Chemistry at an Amido Pincer Complex of Platinum(II)

Harkins, Seth B. and Peters, Jonas C. (2002) Base-Promoted Benzene C−H Activation Chemistry at an Amido Pincer Complex of Platinum(II). Organometallics, 21 (9). pp. 1753-1755. ISSN 0276-7333. doi:10.1021/om011044z. https://resolver.caltech.edu/CaltechAUTHORS:20140722-122514070

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Abstract

The thermally robust platinum(II) complex (BQA)Pt(OTf) undergoes benzene C−H bond activation at 150 °C but requires the presence of N^iPr_2Et. The reaction products are the phenyl complex (BQA)Pt(Ph) and a stoichiometric equivalent of [HN^iPr_2Et][OTf].


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/om011044zDOIArticle
http://pubs.acs.org/doi/abs/10.1021/om011044zPublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/om011044zPublisherSupporting Information
ORCID:
AuthorORCID
Peters, Jonas C.0000-0002-6610-4414
Additional Information:© 2002 American Chemical Society. Received December 7, 2001; Publication on Web 04/02/2002. We thank BP, Caltech, and the Dreyfus Foundation for financial support of this work and Larry Henling for crystallographic assistance. Members of the Bercaw group are thanked for insightful discussions.
Funders:
Funding AgencyGrant Number
BPUNSPECIFIED
CaltechUNSPECIFIED
Camille and Henry Dreyfus FoundationUNSPECIFIED
Issue or Number:9
DOI:10.1021/om011044z
Record Number:CaltechAUTHORS:20140722-122514070
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140722-122514070
Official Citation:Harkins, S. B., & Peters, J. C. (2002). Base-Promoted Benzene C−H Activation Chemistry at an Amido Pincer Complex of Platinum(II). Organometallics, 21(9), 1753-1755. doi: 10.1021/om011044z
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:47399
Collection:CaltechAUTHORS
Deposited By: Joanne McCole
Deposited On:22 Jul 2014 22:25
Last Modified:10 Nov 2021 17:39

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