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Transition metal complexes supported by (8-quinolynyl)amido ligands

Peters, Jonas C. and Betley, Theodore A. and Brown, Steven D. and Harkins, Seth B. and Qian, Baixin (2001) Transition metal complexes supported by (8-quinolynyl)amido ligands. Abstracts of Papers of the American Chemical Society, 221 . INOR 662. ISSN 0065-7727 . https://resolver.caltech.edu/CaltechAUTHORS:20140723-080337837

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Abstract

Our program is targeting the preparation of reactive transition metal complexes suitable for the activation and functionalization of small molecule substrates. As part of this effort we have prepared a series of anionic, chelating amido ligands derived from 8-aminoquinoline utilizing Pd-coupling methods. Thus far, a host of Group VIII, IX, and X transition metal systems has been developed from the parent BQA (BQA = bis(8-quinolynyl)amide) ligand, such as those examples depicted below. The preparative chemistry enabling access to these and several second generation systems will be discussed, in addition to their unfolding reaction chemistry.


Item Type:Article
Additional Information:© 2001 American Chemical Society.
Record Number:CaltechAUTHORS:20140723-080337837
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140723-080337837
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:47412
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:23 Jul 2014 15:46
Last Modified:03 Oct 2019 06:53

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