Jenkins, David M. and Betley, Theodore A. and Peters, Jonas C. (2002) Oxidative Group Transfer to Co(I) Affords a Terminal Co(III) Imido Complex. Journal of the American Chemical Society, 124 (38). pp. 11238-11239. ISSN 0002-7863. doi:10.1021/ja026852b. https://resolver.caltech.edu/CaltechAUTHORS:20140723-094451859
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Abstract
The synthesis of the first terminal imido complex of cobalt, [PhBP3]CoN-p-tolyl, is reported. Its synthesis proceeds by oxidative group transfer from cobalt(I) upon addition of tolyl azide at room temperature. This species and a related η1-diazoalkane adduct have been structurally characterized. The diamagnetic imido complex [PhBP3]CoN-p-tolyl reacts with CO to liberate isocyanate and the cobalt(I) dicarbonyl complex [PhBP_(3)]Co(CO)_(2).
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| Additional Information: | © 2002 American Chemical Society. Received May 9, 2002. We thank the NSF (CHE-0132216), the ACS PRF, and the Dreyfus Foundation for financial support. D.M.J. is grateful for an NSF predoctoral fellowship. The authors acknowledge J. Christopher Thomas for assistance with preliminary DFT calculations and Dr. Daniel Mindiola for insightful discussions. | ||||||||||||
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| Issue or Number: | 38 | ||||||||||||
| DOI: | 10.1021/ja026852b | ||||||||||||
| Record Number: | CaltechAUTHORS:20140723-094451859 | ||||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20140723-094451859 | ||||||||||||
| Official Citation: | Oxidative Group Transfer to Co(I) Affords a Terminal Co(III) Imido Complex David M. Jenkins,Theodore A. Betley, and, and Jonas C. Peters Journal of the American Chemical Society 2002 124 (38), 11238-11239 | ||||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
| ID Code: | 47419 | ||||||||||||
| Collection: | CaltechAUTHORS | ||||||||||||
| Deposited By: | Jason Perez | ||||||||||||
| Deposited On: | 23 Jul 2014 19:03 | ||||||||||||
| Last Modified: | 10 Nov 2021 17:39 |
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