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Oxidative Group Transfer to Co(I) Affords a Terminal Co(III) Imido Complex

Jenkins, David M. and Betley, Theodore A. and Peters, Jonas C. (2002) Oxidative Group Transfer to Co(I) Affords a Terminal Co(III) Imido Complex. Journal of the American Chemical Society, 124 (38). pp. 11238-11239. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20140723-094451859

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Abstract

The synthesis of the first terminal imido complex of cobalt, [PhBP3]CoN-p-tolyl, is reported. Its synthesis proceeds by oxidative group transfer from cobalt(I) upon addition of tolyl azide at room temperature. This species and a related η1-diazoalkane adduct have been structurally characterized. The diamagnetic imido complex [PhBP3]CoN-p-tolyl reacts with CO to liberate isocyanate and the cobalt(I) dicarbonyl complex [PhBP_(3)]Co(CO)_(2).


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja026852bDOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja026852bPublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/ja026852bPublisherSupporting Information
ORCID:
AuthorORCID
Peters, Jonas C.0000-0002-6610-4414
Additional Information:© 2002 American Chemical Society. Received May 9, 2002. We thank the NSF (CHE-0132216), the ACS PRF, and the Dreyfus Foundation for financial support. D.M.J. is grateful for an NSF predoctoral fellowship. The authors acknowledge J. Christopher Thomas for assistance with preliminary DFT calculations and Dr. Daniel Mindiola for insightful discussions.
Funders:
Funding AgencyGrant Number
NSFCHE-0132216
American Chemical Society Petroleum Research FundUNSPECIFIED
Camille and Henry Dreyfus FoundationUNSPECIFIED
NSF predoctoral fellowshipUNSPECIFIED
Issue or Number:38
Record Number:CaltechAUTHORS:20140723-094451859
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140723-094451859
Official Citation:Oxidative Group Transfer to Co(I) Affords a Terminal Co(III) Imido Complex David M. Jenkins,Theodore A. Betley, and, and Jonas C. Peters Journal of the American Chemical Society 2002 124 (38), 11238-11239
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:47419
Collection:CaltechAUTHORS
Deposited By: Jason Perez
Deposited On:23 Jul 2014 19:03
Last Modified:26 Nov 2019 11:15

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