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Solution and Solid-State Spin-Crossover Behavior in a Pseudotetrahedral d^7 Ion

Jenkins, David M. and Peters, Jonas C. (2003) Solution and Solid-State Spin-Crossover Behavior in a Pseudotetrahedral d^7 Ion. Journal of the American Chemical Society, 125 (37). pp. 11162-11163. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20140723-132440365

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Abstract

This Communication describes a pseudotetrahedral d^(7) complex, [PhBP_(3)]Co(OSiPh_(3)), that exhibits thermally induced spin-crossover both in solution and in the solid state. Magnetic crossover behavior is achieved by confluence of the X-type ligand and the tripodal auxiliary employed. Four-coordinate platforms of the present geometry type may offer a new approach to magnetic spin-crossover behavior distinct from their electronically related pseudooctahedral counterparts.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja036198fDOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja036198fPublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/ja036198fPublisherSupporting Information
ORCID:
AuthorORCID
Peters, Jonas C.0000-0002-6610-4414
Alternate Title:Solution and Solid-State Spin-Crossover Behavior in a Pseudotetrahedral d7 Ion
Additional Information:© 2003 American Chemical Society. Received May 16, 2003. Publication Date (Web): August 22, 2003. We thank the NSF (CHE-0132216) and the DOE (PECASE) for financial support. D.M.J. acknowledges an NSF graduate research fellowship. We are grateful to the Beckman Institute (Caltech) for use of the SQUID magnetometer, and to Mike Day and Larry Henling for crystallographic assistance.
Funders:
Funding AgencyGrant Number
NSFCHE-0132216
Department of Energy (DOE) PECASE awardUNSPECIFIED
NSF Graduate Research FellowshipUNSPECIFIED
Issue or Number:37
Record Number:CaltechAUTHORS:20140723-132440365
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140723-132440365
Official Citation:Solution and Solid-State Spin-Crossover Behavior in a Pseudotetrahedral d7 Ion David M. Jenkins and and Jonas C. Peters Journal of the American Chemical Society 2003 125 (37), 11162-11163
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:47430
Collection:CaltechAUTHORS
Deposited By: Jason Perez
Deposited On:24 Jul 2014 17:19
Last Modified:26 Nov 2019 11:15

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