Solution and Solid-State Spin-Crossover Behavior in a Pseudotetrahedral d^7 Ion

Jenkins, David M. and Peters, Jonas C. (2003) Solution and Solid-State Spin-Crossover Behavior in a Pseudotetrahedral d^7 Ion. Journal of the American Chemical Society, 125 (37). pp. 11162-11163. ISSN 0002-7863. doi:10.1021/ja036198f. https://resolver.caltech.edu/CaltechAUTHORS:20140723-132440365

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Abstract

This Communication describes a pseudotetrahedral d^(7) complex, [PhBP_(3)]Co(OSiPh_(3)), that exhibits thermally induced spin-crossover both in solution and in the solid state. Magnetic crossover behavior is achieved by confluence of the X-type ligand and the tripodal auxiliary employed. Four-coordinate platforms of the present geometry type may offer a new approach to magnetic spin-crossover behavior distinct from their electronically related pseudooctahedral counterparts.

Item Type:

Article

Related URLs:

URL	URL Type	Description
http://dx.doi.org/10.1021/ja036198f	DOI	Article
http://pubs.acs.org/doi/abs/10.1021/ja036198f	Publisher	Article
http://pubs.acs.org/doi/suppl/10.1021/ja036198f	Publisher	Supporting Information

ORCID:

Author	ORCID
Peters, Jonas C.	0000-0002-6610-4414

Alternate Title:

Solution and Solid-State Spin-Crossover Behavior in a Pseudotetrahedral d7 Ion

Additional Information:

© 2003 American Chemical Society. Received May 16, 2003. Publication Date (Web): August 22, 2003. We thank the NSF (CHE-0132216) and the DOE (PECASE) for financial support. D.M.J. acknowledges an NSF graduate research fellowship. We are grateful to the Beckman Institute (Caltech) for use of the SQUID magnetometer, and to Mike Day and Larry Henling for crystallographic assistance.

Funders:

Funding Agency	Grant Number
NSF	CHE-0132216
Department of Energy (DOE) PECASE award	UNSPECIFIED
NSF Graduate Research Fellowship	UNSPECIFIED

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DOI:

10.1021/ja036198f

Record Number:

CaltechAUTHORS:20140723-132440365

Persistent URL:

https://resolver.caltech.edu/CaltechAUTHORS:20140723-132440365

Official Citation:

Solution and Solid-State Spin-Crossover Behavior in a Pseudotetrahedral d7 Ion David M. Jenkins and and Jonas C. Peters Journal of the American Chemical Society 2003 125 (37), 11162-11163

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ID Code:

47430

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CaltechAUTHORS

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Deposited On:

24 Jul 2014 17:19

Last Modified:

10 Nov 2021 17:39

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