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Chemistry of water-soluble Pt-diimine complexes relevant to C-H bond activation

Balzarek, Christoph and Labinger, Jay A. and Bercaw, John E. (2001) Chemistry of water-soluble Pt-diimine complexes relevant to C-H bond activation. Abstracts of Papers of the American Chemical Society, 221 . INOR 201. ISSN 0065-7727 . http://resolver.caltech.edu/CaltechAUTHORS:20140723-153427748

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Abstract

Detailed mechanistic studies of selective catalytic alkane oxidation with Pt complexes have revealed that the reaction pathway includes the following steps: Initial C-H bond activation at a Pt(ll) center leads to formation of a Pt(ll) alkyl complex which in turn is oxidized in the second step to a hexacoordinate Pt(IV) species. Most mechanistic studies have been carried out with Pt-complex bearing bidentate N-ligands (diamines, diimines) in non-aqueous solvents, while the early work by Shilov et al. on Pt-catalyzed hydrocarbon functionalization was carried out in aqueous solution. To relate the diaminel diimine model chemistry to the Shilov chemistry in water, the water-soluble Pt-complex 1 was prepared. The results of synthetic and mechanistic studies of 1 in water will be presented.


Item Type:Article
ORCID:
AuthorORCID
Labinger, Jay A.0000-0002-1942-9232
Additional Information:© 2001 American Chemical Society.
Record Number:CaltechAUTHORS:20140723-153427748
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20140723-153427748
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:47440
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:23 Jul 2014 22:58
Last Modified:22 Sep 2017 18:40

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