Balzarek, Christoph and Labinger, Jay A. and Bercaw, John E. (2001) Chemistry of water-soluble Pt-diimine complexes relevant to C-H bond activation. Abstracts of Papers of the American Chemical Society, 221 . INOR 201. ISSN 0065-7727. https://resolver.caltech.edu/CaltechAUTHORS:20140723-153427748
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Abstract
Detailed mechanistic studies of selective catalytic alkane oxidation with Pt complexes have revealed that the reaction pathway includes the following steps: Initial C-H bond activation at a Pt(ll) center leads to formation of a Pt(ll) alkyl complex which in turn is oxidized in the second step to a hexacoordinate Pt(IV) species. Most mechanistic studies have been carried out with Pt-complex bearing bidentate N-ligands (diamines, diimines) in non-aqueous solvents, while the early work by Shilov et al. on Pt-catalyzed hydrocarbon functionalization was carried out in aqueous solution. To relate the diaminel diimine model chemistry to the Shilov chemistry in water, the water-soluble Pt-complex 1 was prepared. The results of synthetic and mechanistic studies of 1 in water will be presented.
Item Type: | Article | ||||
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ORCID: |
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Additional Information: | © 2001 American Chemical Society. | ||||
Record Number: | CaltechAUTHORS:20140723-153427748 | ||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20140723-153427748 | ||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||
ID Code: | 47440 | ||||
Collection: | CaltechAUTHORS | ||||
Deposited By: | Tony Diaz | ||||
Deposited On: | 23 Jul 2014 22:58 | ||||
Last Modified: | 03 Oct 2019 06:53 |
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