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C-H bond activation at Pt(II): A route to selective alkane oxidation

Labinger, Jay A. (2002) C-H bond activation at Pt(II): A route to selective alkane oxidation. Abstracts of Papers of the American Chemical Society, 223 . INOR 159. ISSN 0065-7727.

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Activation of C-H bonds by Pt(ll) complexes under mild conditions has been demonstrated in a number of stoichiometric examples. It has also been implicated in alkane oxidations catalyzed by Pt(ll), although no practical application has yet been achieved. An effective process for selective oxidation of alkanes requires optimization of C-H activation as well as its integration with several more key steps that add up to an overall catalytic system. I will report on recent investigations into the mechanism of C-H activation at Pt(ll) aimed ultimately at elucidating the features required to accomplish that goal.

Item Type:Article
Labinger, Jay A.0000-0002-1942-9232
Additional Information:© 2002 American Chemical Society.
Record Number:CaltechAUTHORS:20140724-133512063
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:47471
Deposited By: Tony Diaz
Deposited On:24 Jul 2014 21:42
Last Modified:03 Oct 2019 06:54

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