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(Phosphino)borate coordination chemistry

Peters, Jonas C. and Jenkins, David M. and Betley, Theodore A. and Thomas, J. Christopher and Lu, Connie C. (2002) (Phosphino)borate coordination chemistry. Abstracts of Papers of the American Chemical Society, 223 . INOR 234. ISSN 0065-7727. https://resolver.caltech.edu/CaltechAUTHORS:20140724-134232603

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Abstract

We are studying a host of complexes that are supported by (phosphino)borate ligands. For example, coordination of a tris(phosphino)borate ligand to a divalent cobalt(ll) center gives rise to a low spin, cobalt(ll) species that is 4-coordinate, psuedo-tetrahedral, and monomeric. Virtually all related complexes are high spin. Moreover, this low spin species can be directly converted to a 4-coordinate, high spin relative by clean oxidation of the phosphine donor ligand. Aspects of this and/or related work will be discussed.


Item Type:Article
ORCID:
AuthorORCID
Peters, Jonas C.0000-0002-6610-4414
Additional Information:© 2002 American Chemical Society.
Record Number:CaltechAUTHORS:20140724-134232603
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140724-134232603
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:47474
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:24 Jul 2014 21:34
Last Modified:26 Nov 2019 11:15

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