CaltechAUTHORS
  A Caltech Library Service

Four-coordinate, 14-electron iron alkyl complexes supported by the tripodal phosphine ligand [PhB(CH_2PiPr_2)_3]^-

Daida, Erin J. and Betley, Theodore A. and Peters, Jonas C. (2004) Four-coordinate, 14-electron iron alkyl complexes supported by the tripodal phosphine ligand [PhB(CH_2PiPr_2)_3]^-. Abstracts of Papers of the American Chemical Society, 227 . INOR 285. ISSN 0065-7727. https://resolver.caltech.edu/CaltechAUTHORS:20140728-154320758

Full text is not posted in this repository.

Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20140728-154320758

Abstract

Recent work in our laboratories has focused on the use of tridentate, anionic phosphine ligands to promote novel reactivity of the late transition metals. The highly electron-releasing, sterically demanding tris(diisopropylphosphino)borate ligand, [PhBP^(iPr3)] ([PhBP^(iPr3)]=[PhB(CH_2PiPr_2)_3]^- has been shown to stabilize coordinatively unsaturated iron complexes with a variety of oxidation states. While 18-electron iron alkyl species are known, four-coordinate, low-electron-count iron alkyl complexes are relatively rare. It was of interest to synthesize monoalkyl complexes on the [PhBP^(ipr3)]Fe platform because of their potential use as carbene precursors. A series of four-coordinate, 14-electron iron(ll) alkyl complexes have been synthesized. The complexes have been characterized by a variety of spectroscopic and electrochemical methods as well as x-ray crystallography. The characterization and reactivity of the alkyl complexes will be described.


Item Type:Article
ORCID:
AuthorORCID
Peters, Jonas C.0000-0002-6610-4414
Alternate Title:Four-coordinate, 14-electron iron alkyl complexes supported by the tripodal phosphine ligand [PhB(CH2PiPr2)3]-
Additional Information:© 2004 American Chemical Society.
Record Number:CaltechAUTHORS:20140728-154320758
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140728-154320758
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:47536
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:29 Jul 2014 18:29
Last Modified:26 Nov 2019 11:15

Repository Staff Only: item control page