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An η^3-H_2SiR_2 Adduct of [{PhB-(CH_2PiPr_2)_3}Fe^(II)H

Thomas, Christine M. and Peters, Jonas C. (2006) An η^3-H_2SiR_2 Adduct of [{PhB-(CH_2PiPr_2)_3}Fe^(II)H. Angewandte Chemie International Edition, 45 (5). pp. 776-780. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20140729-085524799

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Abstract

Reaction of the high-spin iron(II) alkyl complex [{PhB(CH_2PiPr_2)_3}FeMe] with phenylsilane or mesitylsilane affords unusual diamagnetic silane adducts of the iron(II) hydride [{PhB(CH_2PiPr_2)_3}FeH]. An η^3 bonding mode in these silane adducts has been established by NMR spectroscopy, X-ray crystallography, and DFT methods. Rapid interconversion of the hydride positions in solution via a silylene intermediate is proposed.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1002/anie.200502527DOIArticle
http://onlinelibrary.wiley.com/doi/10.1002/anie.200502527/abstractPublisherArticle
http://onlinelibrary.wiley.com/doi/10.1002/anie.200502527/suppinfoRelated ItemSupporting Information
ORCID:
AuthorORCID
Peters, Jonas C.0000-0002-6610-4414
Additional Information:© 2006 Wiley-VCH Verlag GmbH & Co. Article first published online: 21 Dec 2005. Manuscript Revised: 12 Oct 2005. Manuscript Received: 19 Jul 2005. This work was supported by the NSF (CHE-01232216) and BP (MC2 program). Larry Henling and Dr. Mike Day are acknowledged for crystallographic assistance, and Erin J. Daida is acknowledged for executing several preliminary screen reactions. We also thank the referees of this manuscript for several insightful suggestions.
Funders:
Funding AgencyGrant Number
NSFCHE-01232216
BP MC2 programUNSPECIFIED
Subject Keywords:borates, iron, phosphanes, silanes
Issue or Number:5
Record Number:CaltechAUTHORS:20140729-085524799
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140729-085524799
Official Citation:Thomas, C. M. and Peters, J. C. (2006), An η3-H2SiR2 Adduct of [{PhB(CH2PiPr2)3}FeIIH]. Angew. Chem. Int. Ed., 45: 776–780. doi: 10.1002/anie.200502527
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:47550
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:29 Jul 2014 16:15
Last Modified:26 Nov 2019 11:15

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