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New facial amidophosphine ligands: Construction and applications

MacKay, Bruce A. and Peters, Jonas C. (2006) New facial amidophosphine ligands: Construction and applications. Abstracts of Papers of the American Chemical Society, 231 . INOR 732. ISSN 0065-7727.

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Amido(bis)phosphines that bind facially to transition metals represent a logical design iteration that offers coordination properties distinct from those of tris(phosphino)borates already studied by our group. Chief among these new properties are the electronic effects resulting from a coordinating hard amido donor, esp. via possible pi donation. A general synthetic scheme that allows parallel variation of functional groups at the N and P donors has been developed, and preliminary coordination chem. is presented and discussed.

Item Type:Article
Peters, Jonas C.0000-0002-6610-4414
Additional Information:© 2006 American Chemical Society.
Record Number:CaltechAUTHORS:20140729-143331272
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:47564
Deposited By: Tony Diaz
Deposited On:30 Jul 2014 18:46
Last Modified:26 Nov 2019 11:15

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